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Chapter 11: Q.11-50f (page 350)
Question:What products would you expect from the reaction of 1-bromopropane with each of the following?
(f) Mg, then H2O
Answer
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Question: Propose structures for compounds that fit the following descriptions:
(b) An organohalide that will not undergo nucleophilic substitution
We saw in Section 8-7 that bromohydrins are converted into epoxides when treated with base. Propose a mechanism, using curved arrows to show the electron flow.
From which alkyl bromide was the following alkyl acetate made SN2 byreaction? Write the reaction, showing all stereochemistry.
Which compound in each of the following pairs will react faster in an SN2reaction with OH-?
(b) CH3CH2Iin ethanol or dimethyl sulfoxide
What effect would you expect the following changes to have on the rate of the reaction of ethanol with 2-iodo-2-methyl butane?
(a) The concentration of the halide is tripled.
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