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Chapter 11: Q.11-50f (page 350)
Question:What products would you expect from the reaction of 1-bromopropane with each of the following?
(f) Mg, then H2O
Answer
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What effect would you expect the following changes to have on the rate of the reaction of ethanol with 2-iodo-2-methyl butane?
(b) The concentration of the ethanol is halved by adding diethyl ether as an inert solvent.
Among the many examples of reactions that occur with incomplete racemization, the optically pure tosylate of 2,2-dimethyl-1-phenyl-1-propan(= 230.3) gives the corresponding acetate (= 15.3) when heated inacetic acid. If complete inversion had occurred, the optically pure acetatewould have had= 153.6. What percentage racemization and what percentageinversion occurred in this reaction?
Assign configuration to the following substrate, and show the stereochemistry and identity of the product you would obtain by reaction with water (reddish-brown=Br):
Which compound in each of the following pairs will react faster in an SN2reaction with OH-?
(c)
Write the product you would expect from reaction of each of the following alkyl halides with (1)Na+-SCH3and (2)Na+-OH(green = Cl):
a)
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