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Chapter 11: Q56A (page 350)

Question: Order each of the following sets of compounds with respect to reactivity:

Short Answer

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Answer

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01

SN2 reaction

It is the substitution nucleophilic unimolecular reaction. It follows first-order kinetics that it is a two-step reaction in which a carbocation intermediate is formed.

The rate of the reaction depends only on the reacting species and is independent of the nucleophile.

02

Reactivity towards SN2 reaction

As the carbocation intermediate is formed in the reaction the reacting species which form the most stable carbocation is more reactive toward the nucleophile.

Stability of carbocation:

  1. 30> 20> 10
  2. If carbocation showing resonance is more stable than non-resonance carbocation

So,

Reactivity order

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Most popular questions from this chapter

(S)-2-Butanol slowly racemizes on standing in dilute sulfuric acid. Explain.

The following Walden cycle has been carried out. Explain the results, and indicate where Walden inversion occurs.

The reaction of HBr with (R)-3-methyl-3-hexanol leads to racemic 3-Bromo-3-methyl hexane. Explain.

Question: Predict the product and give the stereochemistry resulting from reaction of each of the following nucleophiles with (R)-2-bromooctane:

(c)CH3S-

Question:What products would you expect from the reaction of 1-bromopropane with each of the following?

(b) KOC(CH3)
See all solutions

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