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Chapter 11: Q56C (page 350)

Question: Order each of the following sets of compounds with respect to reactivity:

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Answer

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01

SN2  reaction

It is the substitution nucleophilic unimolecular reaction. It follows first-order kinetics that it is a two-step reaction in which a carbocation intermediate is formed.

The rate of the reaction depends only on the reacting species and is independent of the nucleophile.

02

Reactivity towards SN2 reaction

As the carbocation intermediate is formed in the reaction the reacting species which form the most stable carbocation is more reactive toward the nucleophile.

Stability of carbocation:

  1. 30 > 20 > 10
  2. If carbocation showing resonance is more stable than non-resonance carbocation

So,

Reactivity order

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Most popular questions from this chapter

Question: Order each of the following sets of compounds with respect to reactivity:

a.

Which reaction in each of the following pairs would you expect to be faster?

(d) Thedisplacement byon bromomethane in benzene or in acetonitrile

Assign configuration to the following substance, and draw the structure of the product that would result from nucleophilic substitution reaction with (reddish brown =Br):

We saw in Section 8-7 that bromohydrins are converted into epoxides when treated with base. Propose a mechanism, using curved arrows to show the electron flow.


Question:What products would you expect from the reaction of 1-bromopropane with each of the following?

(e) Na+-C≡CH
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