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Chapter 5: Q4P (page 120)

Question:Identify the chirality centers in the following molecules (green5Cl, yellow-green5F):

Short Answer

Expert verified

Answer

(a)

b

Step by step solution

01

About chirality centers

If a carbon atom gets attached to four bonds of different substituents or groups, then that carbon is said to be a chirality center. The substituents should not be the same around the carbon.

02

About threose

The molecular formula of this compound is . The actual structure is given below.

Threose

03

About the chirality centers in threose

There are two chirality centers. It is shown below.

Chirality centers

Chirality centers

04

About enflurane

The halogenated ether with molecular formula of is enflurane. The actual structure is given below.

Enflurane

05

About the chirality centers in enflurane

There is one chirality center. It is shown below.

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Most popular questions from this chapter

What is the relationship between the specific rotations of (2R,3R)-dichloropentane and (2S,3S)-dichloropentane? Between (2R,3S)-dichloropentane and (2R,3R)-dichloropentane?

The dehydration of citrate to yield cis-aconitate, a step in the citric acid cycle, involves the pro-R “arm” of citrate rather than the pro-S arm. Which of the following two products is formed?

Which of the following objects are chiral?

(a) A basketball

(b) A fork

(c) A wine glass

(d) A golf club

(e) A spiral staircase

(f) A snowflake

(c)

A 1.50 g sample of coniine, the toxic extract of poison hemlock, was dissolved in 10.0 mL of ethanol and placed in a sample cell with a 5.00 cm pathlength. The observed rotation at the sodium D line was 11.21°. Calculate [α]D for coniine.

Assign R or S configurations to the chirality centers in the followingmolecules:

a.

b.

c.
See all solutions

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