Chapter 12: Q12-46 (page 354)
Ketones undergo a reduction when treated with sodium borohydride, . What is the structure of the compound produced by reaction of 2-butanone with if it has an IR absorption at and in the mass spectrum?
Chapter 12: Q12-46 (page 354)
Ketones undergo a reduction when treated with sodium borohydride, . What is the structure of the compound produced by reaction of 2-butanone with if it has an IR absorption at and in the mass spectrum?
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Get started for freeFrom what alkyne might each of the following substances have been made? (Green = Cl.)
Predict the products for the reactions in Problem 8-26 if each were run in DMSO with water. Show the complete mechanism including appropriate regiochemistry and stereochemistry.
The amount of energy required to spin-flip a nucleus depends both on the strength of the external magnetic field and on the nucleus. At a field strength
of 4.7 T, rf energy of 200 MHz is required to bring a nucleus into resonance,
but energy of only 187 MHz will bring a nucleus into resonance. Calculate
the amount of energy required to spin-flip a nucleus. Is this amount greater
or less than that required to spin-flip a nucleus?
Assume that you are carrying out the dehydration of 1-methyl cyclohexanol to yield 1-methyl cyclohexene. How could you use infrared spectroscopy to determine when the reaction is complete?
Question: What functional groups might the following molecules contain?
(a) A compound with a strong absorption at 1710
(b) A compound with a strong absorption at 1540
(c) A compound with strong absorptions at 1720 and 2500 to 3100
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