Chapter 12: Q12P (page 385)
Where might the following compound have IR absorptions?
Short Answer
Absorption bands seen at 2210-2260 cm-1 , 1690 cm-1and 1640-1680cm-1 .
Chapter 12: Q12P (page 385)
Where might the following compound have IR absorptions?
Absorption bands seen at 2210-2260 cm-1 , 1690 cm-1and 1640-1680cm-1 .
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Get started for freeThe Favorskii reactioninvolves the treatment of an -bromo ketone with a base to yield a ring-contracted product. For example, the reaction of 2-bromocyclohexanone with aqueous NaOH yields cyclopentanecarboxylic acid. Propose a mechanism.
One consequence of the base-catalyzed isomerization of unsaturated ketones described in Problem 22-55 is that 2-substituted 2-cyclopentenones can be interconverted with 5-substituted 2-cyclopentenones. Propose a mechanism for this isomerization.
Predict the product(s) and provide the mechanism for each reaction below. What does each mechanism have in common?
b.
c.
d.
Question: How might you use IR spectroscopy to distinguish between the following pairs of isomers?
Question: Grignard reagents undergo a general and very useful reaction with
ketones. Methylmagnesium bromide, for example, reacts with cyclohexanoneto yield a product with the formula . What is the structure of this product if it has an IR absorption at ?
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