Question: 21-66 Assign structures to compounds with the following ¹H N MR spectra:

$$\begin{gathered} \left(a\right){\mathbf{C}}_{\mathbf{4}}\mathbf{}{\mathbf{H}}_{\mathbf{7}}\mathbf{}\mathbf{ClO} \\ \mathbf{IR}\mathbf{}\mathbf{:}\mathbf{1810}\mathbf{}{\mathbf{cm}}^{\mathbf{-}\mathbf{1}} \end{gathered}$$

$$\begin{gathered} \left(b\right){\mathbf{C}}_{\mathbf{6}\mathbf{}}{\mathbf{H}}_{\mathbf{7}}\mathbf{}{\mathbf{NO}}_{\mathbf{2}} \\ \mathbf{IR}\mathbf{:}\mathbf{2250}\mathbf{,}\mathbf{1735}\mathbf{}{\mathbf{cm}}^{\mathbf{-}\mathbf{1}} \end{gathered}$$

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