Chapter 13: Q 57P (page 419)
Question: The NMR spectra of compound A, , are shown. Propose a structure for A, and assign peaks in the spectra to your structure.
Chapter 13: Q 57P (page 419)
Question: The NMR spectra of compound A, , are shown. Propose a structure for A, and assign peaks in the spectra to your structure.
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Get started for freePropose structures for compounds that fit the following descriptions:
(a) A hydrocarbon with seven lines in its 13C NMR spectrum
(b) A six-carbon compound with only five lines in its 13C NMR spectrum
(c) A four-carbon compound with three lines in its 13C NMR spectrum
The following compounds all show a single line in their NMR spectra. List them in order of expected increasing chemical shift:
,cyclohexane ,,benzene
Propose structures for compounds that fit the following 1H NMR data:
a.
2.18(3H, singlet)
4.16(2H, doublet j=7Hz)
5.71(1H, triplet j=7Hz)
b.
1.30(9H, singlet)
7.30(5H, singlet)
c.
2.11(3H, singlet)
3.52(2H, triplet j=6Hz)
5.71(2H, triplet j=6Hz)
d.
2.15(2H, quintent j=7Hz)
2.75(2H, triplet j=7Hz)
3.38(2H, triplet j=7Hz)
7.22(5H, singlet)
Identify the indicated sets of protons as unrelated, homotopic, enantiotopic, or diastereotopic:
a.
b.
c.
How many signals would you expect each of the following molecules to have in its and spectra?
a.
b.
c.
d.
e.
f.
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