Chapter 13: Q13-41E (page 419)
Identify the indicated sets of protons as unrelated, homotopic, enantiotopic, or diastereotopic:
Short Answer
- Homotopic
- Enantiotopic
- Diastereotopic
Chapter 13: Q13-41E (page 419)
Identify the indicated sets of protons as unrelated, homotopic, enantiotopic, or diastereotopic:
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Get started for freeQuestion: The following1H NMR absorptions were obtained on a spectrometer
operating at 200 MHz and are given in hertz downfield from the TMS
standard. Convert the absorptions tounits.
(a)436 Hz(b)956 Hz(c)1504 Hz
Propose a structure for compound C, which has = 86 in its mass spectrum, an IR absorption at 3400, and the following NMR spectral data:
Compound C Broadband-decoupled NMR: 30.2, 31.9, 61.8, 114.7, 138.4 d DEPT-90: 138.4 d DEPT-135: positive peak at 138.4 d; negative peaks at 30.2, 31.9, 61.8, 114.7 d
Question: The mass spectrum and NMR spectrum of a hydrocarbon are shown. Propose a structure for this hydrocarbon, and explain the spectral data.
Each of the following compounds has a single NMR peak. Approximately where would you expect each compound to absorb?
Long-range coupling between protons more than two carbon atoms apart is sometimes observed when p bonds intervene. An example is found in 1-methoxy-1-buten-3-yne. Not only does the acetylenic proton, , couple with the vinylic proton , it also couples with the vinylic proton , four carbon atoms away. The data are:
Construct tree diagrams that account for the observed splitting patterns of ,, and .
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