Show that the following functions have exact differentials: (a) \(x^{2} y+3 y^{2}\), (b) \(x \cos x y\), (c) \(x^{3} y^{2}\), (d) \(t\left(t+e^{3}\right)+s\).

Short Answer

Expert verified
All four functions have exact differentials, as for each function, \( \frac{\partial F_x}{\partial y} = \frac{\partial F_y}{\partial x}\) or \( \frac{\partial F_t}{\partial s} = \frac{\partial F_s}{\partial t}\), satisfying the condition for exactness.

Step by step solution

01

Understanding Exact Differentials

A function has an exact differential if it can be written as the derivative of another function with respect to one variable, holding the other variables constant. This can be expressed as the function being the total differential of a potential function. For example, if a function has the form F(x, y), an exact differential has the form \(dF = F_x dx + F_y dy\text{, where } F_x = \frac{\partial F}{\partial x}\text{ and } F_y = \frac{\partial F}{\partial y}\). The function will have an exact differential if \( \frac{\partial F_x}{\partial y} = \frac{\partial F_y}{\partial x}\).
02

Verifying Exactness for Function (a) \(x^{2} y+3y^{2}\)

Differentiate \(x^{2} y+3y^{2}\) with respect to x to find \(F_x\), and similarly differentiate it with respect to y to find \(F_y\): \begin{align*} F_x &= \frac{\partial}{\partial x}(x^{2} y+3y^{2}) = 2xy, \ F_y &= \frac{\partial}{\partial y}(x^{2} y+3y^{2}) = x^{2} + 6y. \end{align*} Now check for exactness: \begin{align*} \frac{\partial F_x}{\partial y} &= 2x, \ \frac{\partial F_y}{\partial x} &= 2x. \end{align*} Since \( \frac{\partial F_x}{\partial y} = \frac{\partial F_y}{\partial x}\), the function \(x^{2} y+3y^{2}\) has an exact differential.
03

Verifying Exactness for Function (b) \(x \cos x y\)

Differentiate \(x \cos xy\) with respect to x to get \(F_x\) and with respect to y to get \(F_y\): \begin{align*} F_x &= \frac{\partial}{\partial x}(x \cos xy) = \cos xy - xy\sin xy, \ F_y &= \frac{\partial}{\partial y}(x \cos xy) = -x^2\sin xy. \end{align*} Verify exactness: \begin{align*} \frac{\partial F_x}{\partial y} &= -x^2\sin xy, \ \frac{\partial F_y}{\partial x} &= -x^2\sin xy. \end{align*} Since \( \frac{\partial F_x}{\partial y} = \frac{\partial F_y}{\partial x}\), the function \(x \cos xy\) has an exact differential.
04

Verifying Exactness for Function (c) \(x^{3} y^{2}\)

Differentiate \(x^{3} y^{2}\) with respect to x to find \(F_x\), and with respect to y to find \(F_y\): \begin{align*} F_x &= \frac{\partial}{\partial x}(x^{3} y^{2}) = 3x^{2}y^{2}, \ F_y &= \frac{\partial}{\partial y}(x^{3} y^{2}) = 2x^{3}y. \end{align*} Check for exactness: \begin{align*} \frac{\partial F_x}{\partial y} &= 6x^{2}y, \ \frac{\partial F_y}{\partial x} &= 6x^{2}y. \end{align*} Since \(\frac{\partial F_x}{\partial y} = \frac{\partial F_y}{\partial x}\), the function \(x^{3} y^{2}\) has an exact differential.
05

Verifying Exactness for Function (d) \(t(t+e^{3})+s\)

Since function (d) involves t and s, differentiate \(t(t+e^{3})+s\) with respect to t to obtain \(F_t\) and with respect to s to obtain \(F_s\): \begin{align*} F_t &= \frac{\partial}{\partial t}(t(t+e^{3})+s) = 2t + e^{3}, \ F_s &= \frac{\partial}{\partial s}(t(t+e^{3})+s) = 1. \end{align*} Verify exactness: \begin{align*} \frac{\partial F_t}{\partial s} &= 0, \ \frac{\partial F_s}{\partial t} &= 0. \end{align*} Since \(\frac{\partial F_t}{\partial s} = \frac{\partial F_s}{\partial t}\), the function \(t(t+e^{3})+s\) has an exact differential.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Partial Derivatives
Partial derivatives are the backbone of multivariable calculus, serving as a fundamental tool for analyzing the behavior of functions with several variables. When dealing with a multivariable function, such as f(x, y), the partial derivative with respect to one variable, say x, is represented as \( \frac{\partial f}{\partial x} \). It measures the rate at which the function changes as the variable x varies, while all other variables are held fixed.

Crucial to understanding exact differentials, partial derivatives allow us to break down complex multivariable functions into simpler slices, reflecting how changes in one direction affect the function's value. In the context of exact differentials, we look for a relationship between the partial derivatives to verify the existence of a potential function whose differential embodies the original multivariable function.
Differential Calculus
Differential calculus focuses on the concept of the derivative, which is a central idea in calculus for understanding how functions change. Fundamentally, differential calculus deals with the calculation of derivatives and their applications, such as rates of change and slopes of curves.

When a function f is differentiable, we can find its differential df, which is an expression approximating the change in f for a small change in its variables. For a function with a single variable, y = f(x), its differential is dy = f'(x)dx. However, with multivariable functions, the total differential involves a sum of terms like df = \( F_x dx + F_y dy \), reflecting contributions from each direction. An exact differential, therefore, is one where this precise form captures the variation in the function across its entire domain.
Multivariable Calculus
Multivariable calculus extends the principles of single-variable calculus to functions with multiple inputs. It teaches us how to handle functions of two or more variables, such as f(x, y), and how to work with their derivatives and integrals.

In relation to exact differentials, multivariable calculus introduces the concept of a potential function, an antecedent whose gradients (or partial derivatives) give rise to the original function. The test for exactness of a differential, as mentioned in the exercise, arises within this framework. If we can show that the mixed partial derivatives of a function's potential counterpart are equal (meaning they are symmetric with respect to interchange of differentiation order: \( \frac{\partial^2 F}{\partial x \partial y} = \frac{\partial^2 F}{\partial y \partial x} \)), we confirm that an exact differential exists.

This principle ensures that our function behaves nicely under integration and that the path taken during integration doesn't alter the outcome—critical for fields like physics and engineering, where such functions often represent physical quantities.

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Most popular questions from this chapter

Concerns over the harmful effects of chlorofluorocarbons on stratospheric ozone have motivated a search for new refrigerants. One such alternative is 2,2 -dichloro-1,1,1-trifluoroethane (refrigerant 123). Younglove and McLinden published a compendium of thermophysical properties of this substance (B.A. Younglove and M. McLinden, \(J\). Phys. Chem. Ref Data 23,7 (1994)), from which properties such as the Joule-Thomson coetficient \(\mu\) can be computed. (a) Compute \(\mu\) at \(1.00\) bar and \(50^{\circ} \mathrm{C}\) given that \((\partial H / \partial p)_{T},=-3.29\) \(\times 10^{3} \mathrm{~J} \mathrm{MPa}^{-1} \mathrm{~mol}^{-1}\) and \(C_{p \cdot m}=110.0 \mathrm{~J} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}\). (b) Compute the temperature change that would accompany adiabatic expansion of \(2.0 \mathrm{~mol}\) of this refrigerant from \(1.5\) bar to \(0.5\) bar at \(50^{\circ} \mathrm{C}\).

Silylene \(\left(\mathrm{SiH}_{2}\right)\) is a key intermediate in the thermal decomposition of silicon hydrides such as silane \(\left(\mathrm{SiH}_{4}\right)\) and disilane \(\left(\mathrm{Si}_{2} \mathrm{H}_{6}\right)\). Moffat et al. (H.K. Moffat, K.F. Jensen, and R.W. Carr, J. Phys. Chem. 95,145 (1991)) report \(\Delta_{1} H\) \(\left.\Theta_{\mathrm{SiH}_{2}}\right)=+274 \mathrm{kl} \mathrm{mol}^{-1} .\) If \(\Delta_{1} H^{\Theta}\left(\mathrm{SiH}_{4}\right)=+34.3 \mathrm{kj} \mathrm{mol}^{-1}\) and \(\Delta_{1} H^{\mathrm{O}}\left(\mathrm{Si}_{2}, \mathrm{H}_{6}\right)\) \(=+80.3 \mathrm{kj} \mathrm{mol}^{-1}\) (CRC Handbook (2004)), compute the standard enthalpies of the following reactions: a. \(\mathrm{SiH}_{4}(\mathrm{~g}) \rightarrow \mathrm{SiH}_{2}(\mathrm{~g})+\mathrm{H}_{2}(\mathrm{~g})\) b. \(\mathrm{Si}_{2} \mathrm{H}_{6}(\mathrm{~g}) \rightarrow \mathrm{SiH}_{2}(\mathrm{~g})+\mathrm{SiH}_{4}(\mathrm{~g})\)

(a) Derive the relation \(C_{v}=-(\partial U / \partial V) \mathrm{T}(\partial V / \partial T)_{u}\) from the expression for the total differential of \(U(T, V)\) and (b) starting from the expression for the total differential of \(H(T, p)\), express \(\left(\partial H / \partial_{p}\right)_{\mathrm{T}} .\) in terms of \(C_{P}\) and the JouleThomson coefficient, \(\mu\).

Another alternative refrigerant (see preceding problem) is \(1,1,1,2\) tetrafluoroethane (refrigerant HFC-134a). Tillner-Roth and Baehr published a compendium of thermophysical properties of this substance (R. Tillner-Roth and H.D. Baehr, \(J\). Phys. Chem. Ref. Data 23, 657 (1994) from which properties such as the Joule-Thomson coefficient \(\mu\) can be computed. (a) Compute \(\mu\) at \(0.100 \mathrm{MPa}\) and \(300 \mathrm{~K}\) from the following data (all referring to \(300 \mathrm{~K}\) ): \(\begin{array}{llll} \text { P/MPa } & 0.080 & 0.100 & 0.12 \\ \text { Specific enthalpy/(k] } \mathrm{kg}^{-1} \text { ) } & 426.48 & 426.12 & 425.76 \end{array}\) (The specific constant-pressure heat capacity is \(\left.0.7649 \mathrm{~kJ} \mathrm{~K}^{-1} \mathrm{~kg}^{-1}\right)\) (b) Computer \(\mu\) at \(1.00 \mathrm{MPa}\) and \(350 \mathrm{~K}\) from the following data (all referring to \(350 \mathrm{~K}\) ): \(\begin{array}{llll} \text { PIMPa } & 0.80 & 1.00 & 1.2 \\ \text { Specific enthalpy/(k] } \mathrm{kg}^{-1} \text { ) } & 461.93 & 459.12 & 456.15 \end{array}\) (The specific constant-pressure heat capacity is \(1.0392 \mathrm{~kJ} \mathrm{~K}^{-1} \mathrm{~kg}^{-1}\).)

Rearrange the van der Waals equation of state to give an expression for \(T\) as a function of \(p\) and \(V\) (with \(\mathrm{n}\) constant). Calculate \((\partial T / \partial p)_{\mathrm{v}}\), and confirm that \((\partial \mathrm{T} / \partial p)_{\mathrm{v}}=1 /(\partial p / \partial \mathrm{T})_{v}\). Go on to confirm Euler's chain relation.

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