You have obtained a sample of a white crystal. line compound which you think is benzoic acic (literature m.pt. \(=121^{\circ} \mathrm{C}\) ) and its m.pt. range is found to be \(120-128,{ }^{\circ} \mathrm{C}\). Draw three possible con clusions from this result.

Short Answer

Expert verified
Possible conclusions: 1. The sample could be benzoic acid, as the melting points match. 2. The broad range suggests that the sample could be impure. 3. Further tests are needed to confirm whether the sample is benzoic acid.

Step by step solution

01

Understanding the significance of melting points

Melting points are often used to identify substances. A pure substance has a specific melting point, while impurities usually cause a decrease in the melting point and cause a broader melting point range.
02

Comparing the measured melting point range with literature value

The literature melting point of benzoic acid is \(121^{\circ} \mathrm{C}\). The measured melting point range of the white crystalline compound sample is \(120-128^{\circ} \mathrm{C}\). The melting point range encompasses the literature melting point of benzoic acid.
03

Drawing conclusions based on the comparison

1. The sample could be benzoic acid since the melting point range includes the literature melting point of benzoic acid. \n2. However, since the melting point range is broad, the sample likely contains impurities. \n3. Without further testing, it's impossible to definitively identify the sample as benzoic acid based solely on the melting point range.

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with Vaia!

Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Substance Identification
The identification of substances in analytical chemistry often hinges on characteristic traits such as their melting point. Melting points give us a unique 'fingerprint' to identify a substance, especially when dealing with crystalline solids. For the student exercise in question, the melting point range of a sample believed to be benzoic acid almost corresponds with the literature value for pure benzoic acid. This can be a strong indicator that the substance in question is indeed benzoic acid, as the experimentally determined melting point of a substance is one of the primary means of substance identification in a laboratory setting.

However, it's worth noting that a melting point alone is not conclusive proof of identity. The presence of a melting point range, rather than a singular melting point, indicates that there may be complicating factors that need further exploration - either impurities or potential mixtures of different compounds.
Purity Assessment
Melting point analysis serves a dual role, also providing invaluable information about the purity of a substance. For pure compounds, melting points tend to be sharp and well-defined, often within a range of one or two degrees Celsius. In contrast, a broader melting point range, as seen in the student exercise with the sample melting between 120 to 128°C, suggests the presence of impurities. These impurities disrupt the crystal lattice of the substance, causing it to melt over a wider range of temperatures.

The degree of melting point depression and breadth of the range can give an indication of the level of impurity. In the educational setting, it is important for students to recognize that while a melting point range that encompasses the literature value suggests similarity to the expected compound, the range's width is also a pivotal clue to the sample's purity.
Benzoic Acid Properties
Benzoic acid is a white crystalline substance known for its antifungal properties and widespread use in the food industry as a preservative. Understanding the properties of benzoic acid, specifically its melting point of 121°C, is essential for analytical procedures. Its structural stability contributes to its sharp melting point when pure. However, in practical applications, benzoic acid could be exposed to impurities that affect this precise melting behavior. Students should recognize that a known compound like benzoic acid will exhibit expected physical properties, such as a melting point, but real-world samples often do not meet the ideal due to environmental exposure or processing methods that can introduce impurities.
Analytical Chemistry
Analytical chemistry is a branch of chemistry that deals with the separation, identification, and quantification of chemical components of natural and artificial materials. The field encompasses a variety of techniques, with melting point analysis being one of the fundamental methods to assess chemical substances. It allows chemists to verify the identity and purity of a compound accurately. In educational settings, practicing analytical techniques like melting point analysis instills the scientific rigor required for accurate and repeatable results. Mastery of these techniques is essential for students pursuing careers in fields that require precise chemical analysis.
Crystal Characterization
Crystal characterization is key to understanding the properties of a substance at a molecular level. The arrangement of atoms within a crystal defines its melting point, as the heat applied during the melting point analysis must disrupt this ordered arrangement in order to transition the substance into a liquid state. In the educational exercise, the white crystalline nature of the sample presumed to be benzoic acid alludes to a structured lattice, which is disrupted upon melting. The extent and sharpness of melting can help interpret the degree of order within a crystal. If the melting point range is wide, it can indicate that the crystalline structure has imperfections or is mixed with other substances, which are vital insights for any aspiring chemist.

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Study anywhere. Anytime. Across all devices.

Sign-up for free