Carry out risk assessments for specific chemical hazards. Look up the hazards associated with the use of the following chemicals and list the appropriate protective measures required to minimise the risk during use in a lab class: (a) ethanol to be used as a recrystallisation solvent for a solid (about \(10 \mathrm{~g}\) ); (b) sodium oxalate to be used to make a volumetric standard solution \((250.00 \mathrm{~mL} ; 0.1 \mathrm{M})\); (c) sodium hydroxide, used in solid form to prepare a dilute solution for neutralisation.

Short Answer

Expert verified
Ethanol's major hazards are its flammability and potential for causing dizziness and eye irritation. Protective measures include using in a well-ventilated area, wearing gloves and safety glasses, and keeping it away from ignition sources. Sodium oxalate is harmful if swallowed and can cause skin and eye irritation. Appropriate protective measures include wearing gloves and eye protection, avoiding dust formation, and thoroughly washing hands post handling. Sodium hydroxide causes severe skin burns and eye damage. It is harmful when inhaled and may be corrosive to metals. Use protective gloves, eye and face protection, and promote good ventilation. Avoid contact with skin, eyes, clothing, and avoid breathing its dust or fumes.

Step by step solution

01

Understanding and Listing Hazards for Ethanol

Research and understand the hazards associated with ethanol. Ethanol is a flammable liquid and vapor, it causes serious eye irritation, and may cause drowsiness or dizziness. Considering it's going to be used as a recrystallisation solvent to handle about 10 g of a solid, the major risk comes from its flammable properties.
02

Protective Measures for Ethanol

Appropriate safety measures include using the chemical in a well-ventilated area or under a fume hood to avoid inhaling fumes. Use heat-resistant gloves and safety glasses to protect the skin and eyes. Keep away from sparks, open flames, hot surfaces, and any other source of ignition.
03

Understanding and Listing Hazards for Sodium Oxalate

Research and comprehend the hazards associated with sodium oxalate. Sodium oxalate is harmful if swallowed, causes serious eye irritation, and may cause skin irritation. Here it is used to make a volumetric standard solution of 250.00 mL and 0.1 M concentration, the risks come mainly from its irritant and toxic properties.
04

Protective Measures for Sodium Oxalate

Safety includes wearing protective gloves, eye protection, and possibly a face shield if there is a risk of splashing. Avoid creating dust when handling the compound. Wash hands thoroughly after handling.
05

Understanding and Listing Hazards for Sodium Hydroxide

Research and understand the hazards associated with sodium hydroxide. Sodium hydroxide causes severe skin burns and eye damage, harmful if inhaled and may be corrosive to metals. It's used in solid form to prepare a dilute solution for neutralisation, posing major risks due to its corrosive properties.
06

Protective Measures for Sodium Hydroxide

Necessary safety measures encompass the use of protective gloves along with wearing eye and face protection. Use only in a well-ventilated area under a fume hood to avoid contact with skin, eyes, and clothing. Take necessary measures to avoid breathing dust or fumes.

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