The density of gas \(A\) is twice that to \(B\) at the same temperature the molecular weight of gas \(B\) is twice that of \(A\). The ratio of pressure of gas \(A\) and \(B\) will be : (a) \(1: 6\) (b) \(1: 1\) (c) \(4: 1\) (d) \(1: 4\)

Short Answer

Expert verified
The ratio of pressure of gas A and B is 4:1.

Step by step solution

01

- Understanding the Relationship Between Density and Molecular Weight

The density (d) of a gas is directly proportional to its molecular weight (M) at constant pressure and temperature according to the formula \( d = \frac{MP}{RT} \), where P is the pressure, R is the universal gas constant, and T is the absolute temperature.
02

- Setting up the Given Information

According to the problem, the density of gas A is twice that of gas B, which we can express as \( d_A = 2d_B \). It is also given that the molecular weight of gas B is twice that of A, which we can express as \( M_B = 2M_A \).
03

- Deriving the Ratio of Pressures of Gas A and B

Since both gases are at the same temperature, we can assume T is constant for both. By using the proportional relationship from Step 1 for both gases, we can write \( d_A = \frac{M_AP_A}{RT} \) and \( d_B = \frac{M_BP_B}{RT} \). Substituting the known relationships of the densities and molecular weights, we get \( 2d_B = \frac{M_AP_A}{RT} \) and \( d_B = \frac{2M_AP_B}{RT} \). On dividing the first equation by the second, we obtain \( 2 = \frac{P_A}{2P_B} \), which simplifies to \( P_A = 4P_B \). Therefore, the ratio of the pressures of gas A to gas B is 4:1.

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with Vaia!

Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Density and Molecular Weight Relationship
Understanding the relationship between the density of a gas and its molecular weight is fundamental to grasping various concepts in chemistry and physics. Gas density is a measure of mass per unit volume, and it’s related to molecular weight through the Ideal Gas Law. Here’s a simple way to break it down: At constant temperature and pressure, if the molecular weight of a gas increases, so does its density. This proportional relationship is essential for predicting how different gases will behave under the same conditions.

In our exercise, we’re told that gas A is twice as dense as gas B (\r\( d_A = 2d_B \)), and that the molecular weight of gas B is twice that of A (\r\( M_B = 2M_A \)). By using these relationships, we can deduce how the properties of one gas compare to the other. It's like having a twin but finding out you both have distinct traits despite your identical appearance. The wonderful thing about this relationship is its predictability, allowing us to solve complex problems with ease.
Ideal Gas Equation
The Ideal Gas Equation, \r\( PV = nRT \), is a cornerstone in understanding gas behavior. It allows us to link together the pressure (P), volume (V), number of moles (n), and absolute temperature (T) of a gas, with R being the universal gas constant. Think of it as a recipe that tells us how gases should behave under ideal conditions. Now, if you modify one of the ingredients (say, increase the pressure), the equation tells us what will happen to the other parts of the recipe (like how the volume will change).

This equation is idealized because it doesn't take into account interactions between gas molecules or the volume occupied by the molecules themselves. Despite these simplifications, it’s incredibly useful for many situations, like our textbook problem. We leverage this equation to relate the molecular weights and densities of the gases to their pressures, helping us solve for the unknown ratio with confidence and a clear understanding of the underlying principles.
Pressure Ratio of Gases
When talking about the pressure ratio of gases, we're comparing the force exerted by one gas to another in a given volume. It's like comparing the strengths of two superheroes by seeing how hard they can each punch through the same block of ice. When we say that the pressure of one gas is twice the pressure of another, we are implying that it exerts twice the force on the walls of its container.

The pressure ratio can tell a lot about how gas will act. If two gases have the same temperature and volume, but different pressures, the one with higher pressure contains more molecules pushing against the walls or is made up of heavier molecules doing the pushing - or a mix of both. In our exercise, we find that the pressure of gas A is four times (\r\( P_A = 4P_B \)) that of gas B. This is a direct result of understanding how molecular weight affects density and, subsequently, how both relate to pressure within the framework of the ideal gas law.

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

At identical temperature and pressure, the rate of diffusion of hydrogen.gas is \(3 \sqrt{3}\) times that of a hydrocarbon having molecular formula \(\mathrm{C}_{n} \mathrm{H}_{2 n-2}\). What is the value of \(n\) ? (a) 1 (b) 4 (c) 3 (d) 8

Which occurs when a substance \(X\) is converted from liquid to vapour phase at the standard boiling point? I. Potential energy of the system decreases II. The distance between molecules increases III. The average kinetic energy of the molecules in both phases are equal (a) I only (b) II only (c) III only (d) II and III only

\(\mathrm{O}_{2}\) and \(\mathrm{SO}_{2}\) gases are filled in ratio of \(1: 3\) by moles in a closed container of \(3 \mathrm{~L}\) at temperature of \(27^{\circ} \mathrm{C}\). The partial pressure of \(\mathrm{O}_{2}\) is \(0.60 \mathrm{~atm}\), the concentration of \(\mathrm{SO}_{2}\) would be (a) \(0.36\) (b) \(0.036\) (c) \(3.6\) (d) 36

The total pressure of a mixture of oxygen and hydrogen is \(1.0 \mathrm{~atm} .\) The mixture is ignited and the water is removed. The remaining gas is pure hydrogen and exerts a pressure of \(0.40 \mathrm{~atm}\) when measured at the same values of \(T\) and \(V\) as the original mixture. What was the composition of the original mixture in mole per cent? (a) \(x_{\mathrm{O}_{2}}=0.2 ; x_{\mathrm{H}_{2}}=0.8\) (b) \(x_{\mathrm{O}_{2}}=0.4 ; x_{\mathrm{H}_{2}}=0.6\) (c) \(x_{\mathrm{O}_{2}}=0.6 ; x_{\mathrm{H}_{2}}=0.4\) (d) \(x_{\mathrm{O}_{2}}=0.8 ; x_{\mathrm{H}_{2}}=0.2\)

Select incorrect statement: (a) we can condense vapour simply by applying pressure (b) to liquefy a gas one must lower the temperature below \(T_{C}\) and also apply pressure (c) at \(T_{C}\), there is no distinction between liquid and vapour state hence density of the liquid is nearly equal to density of the vapour (d) However great the pressure applied, a gas cannot be liquified below it's critical temp.

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.

Sign-up for free