Chapter 3: Problem 94
Two flasks \(A\) and \(B\) have equal volumes. \(A\) is maintained at \(300 \mathrm{~K}\) and \(B\) at \(600 \mathrm{~K}\), while \(A\) contains \(\mathrm{H}_{2}\) gas, \(B\) has an equal mass of \(\mathrm{CO}_{2}\) gas. Find the ratio of total K.E. of gases in flask \(A\) to that of \(B\). (a) \(1: 2\) (b) \(11: 1\) (c) \(33: 2\) (d) \(55: 7\)
Short Answer
Step by step solution
Understanding the Kinetic Theory of Gases
Calculate the Ratio of Temperatures
Account for Different Gases
Determine the Ratio of Kinetic Energies
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Kinetic Theory of Gases
One of the key implications of this theory is that the temperature of a gas is directly related to the average kinetic energy of its particles. This means that if you increase the temperature of a gas, you are essentially increasing the energy with which the particles are moving around. As a result, understanding the kinetic energy of gases helps scientists predict how a gas will behave under different temperature conditions. It's like understanding how energetic a crowd of people is—if they are more energetic, they are likely to be much more lively and active, much like the particles in a warmer gas.
Avogadro's Law
This law is incredibly useful when comparing different gases under identical conditions. For example, if two balloons, one filled with helium and the other with nitrogen, are of the same size and are in the same room, Avogadro's Law tells us that they both contain the same number of gas molecules, regardless of the type of gas. So, when it comes to comparing the kinetic energies of different gases in equal volumes, as long as temperature and pressure are unchanged, this law simplifies the work by eliminating the need to consider the type of gas.
Temperature and Kinetic Energy Relationship
For gases, this relationship is beautifully straight-forward: double the temperature (in Kelvin), and you double the average kinetic energy of the gas particles. So, in the context of our original problem, when flask A is at 300 K and flask B at 600 K, flask B's particles have, on average, twice the kinetic energy compared to those in flask A. But since the problem also tells us that each gas has equal mass, and thanks to Avogadro's Law, that means each gas also has the same number of moles. So, the gases' different natures don't complicate things too much because the factors of molar mass cancel out.
Understanding this relationship is crucial because it tells us how a gas will behave when heated or cooled. Just like you know you'll have more energy on a warm, sunny day compared to a cold one, a gas will have particles zipping around faster when the temperature rises and moving more sluggishly when it's cooler.