Chapter 8: QBE (page 182)
Find the activity (not the activity coefficient) of the (tetra propylammonium) ion in a solution containing
Short Answer
The activity of ion is 0.0046.
Chapter 8: QBE (page 182)
Find the activity (not the activity coefficient) of the (tetra propylammonium) ion in a solution containing
The activity of ion is 0.0046.
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Which statements are true In the ionic strength range
activity coefficients decrease with
a) increasing ionic strength
b) increasing ionic charge
c) decreasing hydrated radius
Ammonia Equilibrium treated by solver. We now use the solve spreadsheet introduced in Figure 8 - 9 for solubility to find the concentration of species in 0.01 M ammonia solution, neglecting activity coefficient. In the systematic treatment of equilibrium of hydrolysis, we have four unknowns and two equilibrium (8-13) , (8-14). Therefore we will estimate the concentration of 4unknowns - 2equilibirum = 2species, for which I choose localid="1663566766281" . Setup the spreadsheet shown below, in which the estimate localid="1663566820791" = 3 appears in B6andB7 . (Estimates comes from the equilibrium 8-17 with . Estimate donot have to be very good for Solver to work. The formula in cell C8 is .
and the formula in the cell C9 is . The mass balance appears in cell F6 and the charge balance appears in cell F7 . Cell F8 has the sum . As described for on page 176, open the solver window and set the Solver Option. Then use the Solver to set the target cell F8 Equal to Min by changing cells B6 : B7 . What are the concentrations of the species? What fraction of ammonia is hydrolyzed. Your answer should agree with those from Goal Seek in Figure 8-8
By interpolation, find for when .
Write the equilibrium expression for with activity coefficients.
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