Material balance. If you intend to measure all the anions and cations in an unknown, one sanity check on your results is that the total positive charge should equal the total negative charge. The table lists concentrations of anions and cations measured in pond water in an undergraduate experiment and expressed in mg/mL.

Find the total concentration of negative and positive charge (mol/L) to assess the quality of the analysis. What do you conclude about this analysis?

Short Answer

Expert verified

The total concentration of negative and positive charge (mol/L) is as follows:

Total cation charge: 0.00202M

Total anion charge: -0.00159M

Step by step solution

01

Calculate the concentration by using equation:

c(species;mol/L)=-valuefromspreadsheetmolar-mass¯(of)anion/cation×10-6/10-3c(totalconcentration)=(species;mol/L)

02

Calculation of values

From the above equation we conclude that

Total cation charge: 0.00202M

Total anion charge: -0.00159M

03

Analysis

From this we can conclude that some concentrations can be inaccurate, or some ionic species were not detected.

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with Vaia!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

Ferritin (molecular mass 450 000), transferrin (molecular mass 80 000), and ferric citrate were separated by molecular exclusion chromatography on Bio-Gel P-300. The column had a length of 37 cm and a 1.5-cm diameter. Eluate fractions of 0.65 mL were collected. The maximum of each peak came at the following fractions: ferritin, 22; transferrin, 32; and ferric citrate, 84. (That is, the ferritin peak came at an elution volume of 22 3 0.65 5 14.3 mL)Assuming that ferritin is eluted at the interstitial volume and that ferric citrate is eluted at Vm, findKavfor transferrin.

Decomposition of dithionite(S2O42-).was studied by chromatography on an anion-exchange column eluted with 20mM tri-sodium 1, 3, 6-napthalenetrisulfonate in 90 vol%H2O/10

vol%CH3CNwith ultraviolet detection at 280 nm. A solution of sodium dithionite stored for 34 days in the absence of air gave five peaks identified asSO32-,SO42-,S2O32-,S2O42-andS2Os2-All the peaks had a negative absorbance. Explain why.

Injection in some homebuilt capillary electrophoresis instruments is performed by raising the sample vial to create a siphon. The pressure exerted by a column of water of heightiswhereis the density of water and gis the acceleration of gravity (9.8m/s2). To what height would you need to raise the sample vial to create the necessary pressure to load the sample in 4.0 s? Is it possible to raise the inlet of this column to this height? How could you obtain the desired pressure?

Figure 26-24 shows the effect on resolution of increasing voltage from 28 to120kV.

(a) What is the expected ratio of migration times (t120kV/t28kV)in the two experiments? Measure the migration times for peak 1 and find the observed ratio.

(b) What is the expected ratio of plates (N120kV/N28kV)in the two experiments?

(c) What is the expected ratio of bandwidths(σ120kV/σ28kV)?

(d) What is the physical reason why increasing voltage decreases bandwidth and increases resolution?

Blue Dextran 2000 was eluted during gel filtration in a volume of 36.4mL from a 40 * 2cm (length diameter) column of Sephadex G-50, which fractionates molecules in the molecular mass range 1500-30000.

(a) At what retention volume would hemoglobin (molecular mass 64000 ) be expected?

(b) Suppose that radioactiveNaCI22, which is not adsorbed on the column, is eluted in a volume of 109.8 mL. What would be the retention volume of a molecule with Kav= 0.65?

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.

Sign-up for free