Chapter 12: Q12D E (page 282)
Calculate the concentration of H2Y2- at the equivalence point in Exercise 12-C
Short Answer
H2Y2- concentration at equivalence point will be 1.1×10-7M
Chapter 12: Q12D E (page 282)
Calculate the concentration of H2Y2- at the equivalence point in Exercise 12-C
H2Y2- concentration at equivalence point will be 1.1×10-7M
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Get started for freeCalculate pCu2+ at each of the following points in the titration of 50.00 mL of 0.001 00 M Cu2+ with 0.00100 M EDTA at pH 11.00 in a solution with [NH3] fixed at 1.00 M:
(a) 0 mL(b) 1.00 mL (c) 45.00 mL (d) 50.00 mL (e) 55.00 mL
The sulfur content of insoluble sulfides that do not readily dissolve in acid can be measured by oxidation with Br2 to .25 Metal ions are then replaced with H+ by an ion-exchange column, and sulfate is precipitated as BaSO4 with a known excess of BaCl2. The excess Ba2+ is then titrated with EDTA to determine how much was present. (To make the indicator end point clearer, a small, known quantity of Zn2+ also is added. The EDTA titrates both the Ba2+ and the Zn2+.) Knowing the excess Ba2+, we can calculate how much sulfur was in the original material. To analyze the mineral sphalerite (ZnS, FM 97.46), 5.89 mg of powdered solid were suspended in a mixture of CCl4 and H2O containing 1.5 mmol Br2. After 1 h at 200 C and 2 h at 500 C, the powder dissolved and the solvent and excess Br2 were removed by heating. The residue was dissolved in 3 mL of water and passed through an ion-exchange column to replace Zn2+ with H+. Then 5.000 mL of 0.014 63 M BaCl2 were added to precipitate all sulfate as BaSO4. After the addition of 1.000 mL of 0.010 00 M ZnCl2 and 3 mL of ammonia buffer, pH 10, the excess Ba2+ and Zn2+ required 2.39 mL of 0.009 63 M EDTA to reach the Calmagite end point. Find the weight percent of sulfur in the sphalerite. What is the theoretical value?
Titration of M with L to form ML and ML2. Use theequation from Problem 12-21, where M is Cu2+ and L is acetate.Consider adding 0.500 M acetate to 10.00 mL of 0.050 0 M Cu2+ atpH 7.00 (so that all ligand is present as , not CH3CO2H).Formation constants forCu(CH3CO2)+ and Cu(CH3CO2)2 aregiven in Appendix I. Construct a spreadsheet in which the inputis pL and the output is [L], VL, [M], [ML], and [ML2]. Prepare agraph showing concentrations of L, M, ML, and ML2as VL rangesfrom 0 to 3 mL
At what pH does ?
A 50.0-mL aliquot of solution containing 0.450 g of MgSO4 (FM 120.37) in 0.500 L required 37.6 mL of EDTA solution for titration. How many milligrams of CaCO3 (FM 100.09) will react with 1.00 mL of this EDTA solution?
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