The standard free energy change for the formation of H2(g)=12O2(g) from H2O(l) is G°=+237.13KJ The reactions are

cathode:2H2O+2e-H2(g)+20H-Anode:H2O12O2(g)+2H++2e-

Calculate the standard voltageE°needed to decompose water into its elements by electrolysis. What does the word standard mean in this question?

Short Answer

Expert verified
  • The standard voltage E = -1.229 V needed to decompose water into its elements by electrolysis.

Step by step solution

01

Definition of Standard free energy:

  • The standard free energy of a substance represents the free energy change associated with the formation of the substance from the elements in their most stable forms as they exist under standard conditions.
02

Step 2: Method of calculating Standard Voltage:

We can calculate standard voltage using this equation:

G=-n.F.E

So, the is,

E=-Gn.FE=-237.13.103j2.96485C/molE=--1.229V

03

Elucidating the word Standard:

  • The word standard mean that the reluctant and products are in standard states.

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