What is the difference between combustion and pyrolysis?

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The difference between combustion and pyrolysis is explained clearly.

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01

Definition of combustion and pyrolysis.

  • Combustion, also known as burning, is a high-temperature exothermic redox chemical reaction that occurs between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, to produce oxidised, often gaseous products in a mixture known as smoke.
  • Pyrolysis is the process of subjecting substances to extremely high temperatures in relatively inert environments in order to facilitate thermal decomposition. It is important to note that the pyrolysis process causes a chemical change in the substance being pyrolyzed (the chemical compositions of the initial reactant feedstock and the final product are different). The term "pyrolysis" has Greek roots and can be roughly translated as "fire separating."
02

Determining the difference between combustion and pyrolysis.

Combustion:

Combustion is a process of heating the substance in presence of excess oxygen in the atmosphere in order to convert:

  • the carbon to carbon dioxide (oxidation)
  • hydrogen to water (oxidation)

Gas chromatography is used for measurements

Pyrolysis:

Pyrolysis (thermal decomposition) is a process of heating the substance in the absence of added oxygen in the atmosphere in order to convert:

  • the oxygen to carbon dioxide (reduction)

Here the substance passes through a catalyst

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Most popular questions from this chapter

LaCoO3+x, has a perovskite structure (Box 19-1) with variable oxygen content. The figure shows the thermogravimetric curve observed when 41.8724m gwere heated in role="math" localid="1665035505591" 5vol%H2inAr.La(II)does not react, but cobalt is reduced to Co(s)

(a) What is the oxidation state of cobalt in the ideal formula LaCoO3

(b) Write the reaction of role="math" localid="1665035588740" LaCoO3withH2 to produce La2O3with(s),Co(s),andH2O(s)

(c) If 41.8724mgofLaCoO3 react completely, what will be the mass of product(La2O3+(Co)?

(d) Write the balanced reaction of role="math" localid="1665035782894" LaCoO3+xwithH2O to produce La2O3,Co,andH2O.If41.8724mgofLaCoO3+1react completely; what will be the mass of solid product? Your answer will be an expression with x in it.

(e) From the observed product mass (37.767mg)at700°c, find x inLaCoO3+x Write the formula of the starting solid.

(f) In part (c), the mass lost from the ideal formula LaCoO3+x, is 4.0877 mg. What is the product nearrole="math" localid="1665035980286" 500°Cwhere the mass is -40.51 mg?

Why are many ionic precipitates washed with electrolyte solution instead of pure water?

Finely ground mineral (0.6324g)was dissolved in 25 mLof boiling 4M HCland diluted with 175mLH2Ocontaining two drops of methyl red indicator. The solution was heated to100oC,and50mL of warm solution containing2.0g(NH4)2C2O4 were slowly added to precipitateCaC2O4.Then6MNH3 was added until the indicator changed from red to yellow, showing that the liquid was neutral or slightly basic. After slow cooling for 1 h, the liquid was decanted and the solid transferred to a filter crucible and washed with cold10.1wt%(NH4)2C2O4 solution five times until noCl- was detected in the filtrate upon addition ofAgNO3 solution. The crucible was dried at 1 h and then at105°C in a furnace for 2 h.

Ca2++C2O42-105°CCaC2O4+H2O(s)500oCCaCO3(s)

FM 40.078 18.5467 g

The mass of the empty crucible was 18.2311 g and the mass of the crucible with CaCO3was 18.5467 g .

(a) Find the wt% Ca in the mineral.

(b) Why is the unknown solution heated to boiling and the precipitant solution, (NH4)2C2O4 also heated before slowly mixing the two?

(c) What is the purpose of washing the precipitate with0.1wt%(NH4)2C2O4?

(d) What is the purpose of testing the filtrate withAgNO3solution?

Determination of sulfur by combustion analysis produces a mixture of SO2and SO3 that can be passed through H2O2to convert both into H2SO4, which is titrated with standard base. When 6.123m g of a substance were burned, the H2SO4 required 3.01mL of0.010576MNaOHfor titration. Find wt% sulfur in the sample.

An organic compound with a formula mass of 417g/molwas analyzed for ethoxyl (CHyCH2O-)groups by the reactions

ROCH2CH3+HIROH+CH3CH2ICH3CH2I+Ag++OH-AgI(s)+CH3CH2OH

A 25.42-mg sample of compound produced How many ethoxyl groups are there in each molecule?

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