Write a balanced equation for the combustion of benzoic acid,C6H5CO2H, to giveCO2 and H2O. How many milligrams of and of will be produced by the combustion of 4.635mgof benzoic acid?

Short Answer

Expert verified

The mass of CO2and H2Oproduced during the combustion of 4.635mg of benzoic acid is 0.01169 and 2.051×10-3grespectively.

Step by step solution

01

Writing a balanced equation.

A balanced equation is a chemical reaction equation in which the total charge and the number of atoms for each element in the reaction are the same for both the reactants and the products. In other words, the mass and charge on both sides of the reaction are balanced.

02

Calculating the moles of benzoic acid.

Consider the following balanced equation of benzoic acid combustion:

C6H5CO2H+152O27CO2+3H2O

To write a balanced equation for the combustion of benzoic acid to give and and calculate the mass of products given by the combustion of of benzoic acid.

Calculating the moles of benzoic acid by the following:

nbenzoicacid=mMnbenzoicacid=4.635×10-3g122.123g/molnbenzoicacid=3.795×10-5mol

03

Calculating the mass of products.

Next calculate the mass of products:

Carbondioxide:

nCO2=7nbenzoicacidnCO2=7×3.795×10-5molnCO2=2.6565×10-4mol

1 mole of benzoic acid gives 7 moles of carbon dioxide

mCO2=n×MmCO2=2.6565×10-4mol×44.010g/molnCO2=0.01169g

Water:

role="math" localid="1663662527422" nH2O=3nbenzoicacidnH2O=3×3.795×10-5molnH2O=1.1385×10-4mol

1 mole of benzoic acid gives 3 moles of water

role="math" localid="1663662547240" mH2O=n×MmH2O=1.1385×10-4mol×18.015g/molnH2O=2.051×10-3g

Therefore the mass of CO2and H2O produced during the combustion of 4.635mg of benzoic acid is 0.01169g and2.051×10-3 respectively.

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Most popular questions from this chapter

Finely ground mineral (0.6324g)was dissolved in 25 mLof boiling 4M HCland diluted with 175mLH2Ocontaining two drops of methyl red indicator. The solution was heated to100oC,and50mL of warm solution containing2.0g(NH4)2C2O4 were slowly added to precipitateCaC2O4.Then6MNH3 was added until the indicator changed from red to yellow, showing that the liquid was neutral or slightly basic. After slow cooling for 1 h, the liquid was decanted and the solid transferred to a filter crucible and washed with cold10.1wt%(NH4)2C2O4 solution five times until noCl- was detected in the filtrate upon addition ofAgNO3 solution. The crucible was dried at 1 h and then at105°C in a furnace for 2 h.

Ca2++C2O42-105°CCaC2O4+H2O(s)500oCCaCO3(s)

FM 40.078 18.5467 g

The mass of the empty crucible was 18.2311 g and the mass of the crucible with CaCO3was 18.5467 g .

(a) Find the wt% Ca in the mineral.

(b) Why is the unknown solution heated to boiling and the precipitant solution, (NH4)2C2O4 also heated before slowly mixing the two?

(c) What is the purpose of washing the precipitate with0.1wt%(NH4)2C2O4?

(d) What is the purpose of testing the filtrate withAgNO3solution?

A 0.649-g sample containing only K2SO4(FM174.27)and (NH4)2SO4(FM132.14)was dissolved in water and treated withBa(NO3)2to precipitate allSO4-2asBaSO4(FM233.39). Find the weight percent ofK2SO4in the sample if 0.977 g of precipitate was formed.

Statistics of coprecipitation. 17In Experiment 1,200.0mL of solution containing 10.0mg of SO42-(from Na2SO4) were treated with excess Bacl2 solution to precipitate BaSO4 containing some coprecipitated Cl-. To find out how much coprecipitated was present, the precipitate was dissolved in 35mL of 98wt%H2SO4 and boiled to liberate , which was removed by bubbling gas through the H2SO4. The HCI/N2 stream was passed into a reagent solution that reacted with to give a color that was measured. Ten replicate trials gave values of 7.8,9.8,7.8,7.8,7.8,7.8,13,7,12.7,13.7, and 12.7. Experiment 2 was identical to the first one, except that the mL solution also contained of from ). Ten replicate trials gave 7.8,10,8,8.8,7.8,6.9, 8.8, 15.7 , 12.7 , 13.7and 14.7μmolCl-.

(a) Find the mean, standard deviation, and 95% confidence interval for Cl-in each experiment.

(b) Is there a significant difference between the two experiments? What does your answer mean?

(c) If there were no coprecipitate, what mass of BaSO4(FM 233.39) would be expected?

(d) If the coprecipitate is (FM 208.23), what is the average mass of precipitate(BaSO4+BaCl2)in Experiment 1. By what percentage is the mass greater than the mass in part (c)?

Explain what is done in thermogravimetric analysis.

A mixture containing only Al2O3(FM 101.96) andFe2O3(FM 159.69) weighs 2.019 g. When heated under a stream ofH2Al2O3is unchanged, butisFe2O3 converted into metallic Fe plusH2O(g)If the residue weighs 1.774 g, what is the weight percent ofFe2O3in the original mixture?

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