Which of the following columns will provide:

(a) highest number of plates?

(b) greatest retention?

(c) highest relative retention?

(d) best separation?

Column1:N=1000;k2=3.9;α=1.16;resolution=0.6Column2:N=5000;k2=3.9;α=1.06;resolution=0.8Column3:N=500;k2=4.7;α=1.31;resolution=1.1Column4:N=2000;k2=2.4;α=1.24;resolution=1.5

Short Answer

Expert verified

The solution is

- a) Column 2 because it has the biggest N value (N = 5000)

- b) Column 3 because it has the largest k2value k2=4.7

- c) Column 3 because it has the largest role="math" localid="1654934451145" αvalue α=1.31

- d) Column 4 because it is the only one with baseline resolution (resolution = 1.5)

Step by step solution

01

of 3

In this task we will determine which of the columns will provide:

a) highest number of plates

b) greatest retention

c) highest relative retention

d) best separation

02

of 3

Column1:N=1000;k2=1.2;α=1.16;resolution=0.6Column2:N=5000;k2=3.9;α=1.06;resolution=0.8Column3:N=500;k2=4.7;α=1.31;resolution=1.1Column4:N=2000;k2=2.4;α=1.24;resolution=1.5

03

of 3

The solution is

- a) Column 2 because it has the biggest N value (N = 5000)

- b) Column 3 because it has the largest k2value k2=4.7

- c) Column 3 because it has the largest αvalue α=1.31

- d) Column 4 because it is the only one with baseline resolution (resolution = 1.5)

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Most popular questions from this chapter

An open tubular column is 30.01 mlong and has an inner diameter of 0.530mm. It is coated on the inside wall with a layer of stationary phase that is3.1μmthick. Unretained solute passes through in 2.16min, whereas a particular solute has a retention time of 17.32min. (a) Find the linear velocity and volume flow rate. (b) Find the retention factor for the solute and the fraction of time spent in the stationary phase.(c) Find the partition coefficient, K 5 cs/cm, for this solute.

(a) Write the meaning of the retention factor,k, in terms of time spent by solute in each phase. (b) Write an expression in terms of kfor the fraction of time spent by a solute molecule in the mobile phase. (c) The retention ratio in chromatography is defined as R=timeforsolventtimeforsolutetopassthroughcolumn=tmtrShow that is related to the retention factor by the equation R=1/k+1

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