Chapter 23: Q44P (page 631)
A chromatogram with ideal Gaussian bands hasand
.
(a) How many theoretical plates are present?
(b) Find the plate height if the column is 10cm long.
Short Answer
The solution is
Chapter 23: Q44P (page 631)
A chromatogram with ideal Gaussian bands hasand
.
(a) How many theoretical plates are present?
(b) Find the plate height if the column is 10cm long.
The solution is
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Get started for freeWhich of the following columns will provide:
(a) highest number of plates?
(b) greatest retention?
(c) highest relative retention?
(d) best separation?
(a) For the asymmetric chromatogram in Figure 23-14, calculate the asymmetry factor, .(b) The asymmetric chromatogram in Figure 23-14 has a retention time equal to 15.0 min and a of 44s . Find the number of theoretical plates. (c) The width of a Gaussian peak at a height equal to of the peak height is . Suppose that the peak in (b) is symmetric with . Use Equations 23-30 and 23-32 to find the plate number.
Consider a chromatography experiment in which two components with retention factors and are injected into column with theoretical plates. The retention time for the less-retained component is .
(a)Calculate and.Find (width at half height) and w (at the base) for each peak.
(b)Using graph paper , sketch the chromatogram analogous to figure 23-7,supposing that two peaks have same amplitude(height). Draw the half widths accurately.
(c)Calculate the resolution of the two peaks and compare this value with those drawn in Figure 23-10.
Consider a chromatography column in which Find the retention factor if K = 3 and if K = 30 .
Why is longitudinal diffusion a more serious problem in gas chromatography than in liquid chromatography?
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