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Chapter 7: Q28P (page 160)

Use Equation 7-12 to reproduce the curves in Figure 7-3. Plot your results on a single graph.

Short Answer

Expert verified

The graph of the silver halide titration curve:

Step by step solution

01

Concept used.

The equation for titration curve of $M^{+}$ with $X^{-}$ is

$V_{M} = {V_{X}}^{°} (\frac{{C_{x}}^{°} + [M^{+} l - [X^{-}]}{C_{M} - [M^{+}] - [X^{-} l})$

$C_{M} i$ is initial concentration of $M^{+}$

$C_{x} is concentration of X^{-} V_{x} is volume of X^{-}$

02

Plot the graph

The graph of a silver halide titration curve.

The spreadsheet for the silver iodide titration curve is as follows:

The graph of the silver halide titration curve looks like this:

As the solubility product of halides declines, so does the solubility of halides. Silver iodide has the steepest slope, indicating that it is least soluble. Because is dependent on the concentration of silver ions, the values rise as the solubility product decreases.

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Most popular questions from this chapter

What is wrong with this procedure? According to Table 7-1, carbonate can be measured by a Volhard titration. Removal of the precipitate is required. To analyse an unknown solution of, ${Na}_{2} {CO}_{3}$ , l acidified the solution with freshly boiled and cooled ${HNO}_{3}$ to give ,0.5 M ${HNO}_{3}$ . Then I added excess standard, but no ${Ag}_{2} {CO}_{3}$ precipitate formed. What happened?

A solid mixture weighing 0.05485 gcontained only ferrous ammonium sulfate and ferrous chloride. The sample was dissolved in $1 {MH}_{2} {SO}_{4}$ , and the ${Fe}^{2 +}$ required 13.39mLof $0.01234 {MCe}^{4 +}$ for complete oxidation to ${Fe}^{3 +} ({Ce}^{4 +} + {Fe}^{2 +} \to {Ce}^{3 +} + {Fe}^{3 +})$ . Calculate the weight percent CI ofin the original sample.

Explain the following statement: “The validity of an analytical

result ultimately depends on knowing the composition of some primary standard.”.

How many milliliters of $0.100 MKI$ are needed to react with $40.0 mL$ of $0.400 {MHg}_{2} ({NO}_{3})$ if the reaction isrole="math" localid="1654768697091" ${Hg}_{2}^{2} + 2 l^{-} \to {Hg}_{2} I_{2} (s)$ ?

Sulfamic acid is a primary standard that can be used to standardize $NaOH .$

$^{+} H_{3} {NSO}_{3}^{-} + OH \to H_{2} {NSO}_{3}^{-} + H_{2} O$ Sulfamic acidFM 97.094What is the molarity of a sodium hydroxide solution if $34.26 mL$ react with $0.3337 g$ of sulfamic acid?

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