A solid sample weighing 0.2376 g contained only malonic acid and aniline hydrochloride. It required 34.02 mLof 0.8771 M NaOH to neutralize the sample. Find the weight percent of each component in the solid mixture. The reactions are.

Short Answer

Expert verified

The percentages of the weight of each species in the given mixture are

%ofaniliniumchloride=57.90%%ofmalonicacid=42.09%

Step by step solution

01

Define the molarity

The total number of moles of solute per litre of solution is known as a solution's molarity. Because, unlike mass, the volume of a system fluctuates with changes in physical conditions, the molality of a solution is affected by changes in physical parameters of the system such as pressure and temperature. Molarity is represented by the letter M, which stands for a molar.

The molarity of a solution is defined as one gramme of solute dissolved in one litre of solution.

02

Calculate the percentage of the weight of each species in the given mixture

Malonic acid makes up 42.09 percent of the weight in a particular composition.

The weight proportion of anilinium chloride in a given combination is 57.90%.

The reaction

CH2(CO22+2OH-CH2(CO2)+2H2OC6H5-NH3+Cl-+OH-C6H5-NH2+H2O+Cl-

Number of moles ofNaOH=34.02mL×0.08771M

=2.9839mmolNaOH

The percentage of anilinium is given by

2(massofmalonicacid)+(massofaniliniumchloride)=0.0029839mol

2massofmalonicacid129.59g/mol+massofaniliniumchloride104.06g/mol=0.0029839mol

y=0.2376-x,thenx=0.10001g

%ofaniliniumchloride=0.13759g0.2376g×100=57.90%

%ofmalonicacid=0.10001g0.2376g×100=42.09%

Thus, the percentage of weight of each species in the given mixture are

%ofaniliniumchloride=57.90%%ofmalonicacid=42.09%

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with Vaia!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

Derive an expression analogous to Equation 7-12 for the titration of M+(concentration, CM0,volume=VM0) with X-(titrant concentration=cx0). Your equation should allow you to compute the volume of titrant (vx)as a function of[x-].

Use Equation 7-12 to reproduce the curves in Figure 7-3. Plot your results on a single graph.

Describe how to analyze a solution of NaI by using the Volhard

titration.

What is wrong with this procedure? According to Table 7-1, carbonate can be measured by a Volhard titration. Removal of the precipitate is required. To analyse an unknown solution of, Na2CO3, l acidified the solution with freshly boiled and cooled HNO3to give ,0.5 M HNO3. Then I added excess standard, but no Ag2CO3precipitate formed. What happened?

Ascorbic acid (vitamin C) reacts with I3-according to the equation

Starch is used as an indicator in the reaction. The end point is marked by the appearance of a deep blue starch-iodine complex when the first fraction of a drop of unreacted I3-remains in the solution.

(a) Verify that the structures above have the chemical formulas written beneath them. You must be able to locate every atom in the formula. Use atomic masses from the periodic table on the inside cover of this book to find the formula mass of ascorbic acid.

(b) If 29.41 mL of I3-solution are required to react with 0.197 0 g of pure ascorbic acid, what is the molarity of the I3-solution?

(c) A vitamin C tablet containing ascorbic acid plus inert binder was ground to a powder, and 0.424 2 g was titrated by 31.63 mL ofI3- . Find the weight percent of ascorbic acid in the tablet.

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.

Sign-up for free