What is a Jones reductor and what is it used for?

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Jones reductor is a reducing substance that can be used to lower the oxidation state of a metal ion in an aqueous solution

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01

Definition of Jones reductor.

A device that is used to chemically decrease liquids, such as ferric salt solutions, by pouring the solution into a vertical tube containing granular zinc.

02

Determine the Jones redactor and uses.

  • Jones reductor is a column that contains zinc coated with zinc amalgam (solution with mercury).

  • Analyte is pre-reduced by passing through the Jones reductor with sulfuric acid as a solvent Analytes that can be reduced with Jones reductor are Fe3+,Sn4andMnO4Uses:

  • A Jones reductor is a reducing substance that can be used to lower the oxidation state of a metal ion in aqueous solution.

  • A zinc amalgam is the active ingredient. It can be used to make solutions of ions that are promptly oxidised when exposed to air, such as Chromium(II), Cr2ι, and uranium(III),U3+.

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Most popular questions from this chapter

Li1+CoO2 is an anode for lithium batteries. Cobalt is present as a mixture of Co (III) and Co (II). Most preparations also contain inert lithium salts and moisture. To find the stoichiometry, Co was measured by atomic absorption and its average oxidation state was measured by a potentiometric tritration.39 For the titration, 25.00mg of solid were dissolved under in 5. mL containing

0.1000MFe2+in 6MH2SO4 plus6MH3PO4to give a clear pink solution:

Co3++Fe2+Co2++Fe3+

Unreacted Fe2+ required 3.228 mL of0.01593MK2Cr2O7 for complete titration.

(a) How many mmol of Co3+ are contained in 25.00mg of the material?

(b) Atomic absorption found 56.4 wt% Co in the solid. What is the average oxidation state of Co ?

(c) Find y in the formulaLi1+CoO2 .

(d) What is the theoretical quotient wt\% Li/wt\% Co in the solid? The observed quotient, after washing away inert lithium salts, was0.1388±0.0006.Is the observed quotient consistent with the average cobalt oxidation state?

The pathogenic bacterium Salmonella enterica uses tetrathionate found in the human gut as an oxidant- just as we useO2to metabolize our food. Write the half-reaction in which tetrathionate serves as an oxidant. Is tetrathionate as powerful an oxidant asO2?

Aqueous glycerol solution weighing 100.0m gwas treated with 50.0 mL of 0.083 7 M Ce4+in 4 MHCIO4at 60°for15minto oxidize glycerol to formic acid.

CH2-CH-CH2|||OHOHOH HCO2H

Glycerol Formic acid

FM92.095

The excess Ce4+ required 12.11mL of 0.044 8 MFe2+to reach a ferroin end point. Find wt%glycerol in the unknown.

A titration of 50.0 mLof unknown Fe2+with 0.100MCeat 25°C , monitored with Pt and calomel electrodes, gave data in the table. Prepare a Gran plot and decide which data lie on a straight line. Find the x-intercept of this line, which is the equivalence volume. Calculate the molarity of Fe2+in the unknown.

Calcium fluorapatite(Ca10(PO4)6F2,FM1008.6)laser crystals were doped with chromium to improve their efficiency. It was suspected that the chromium could be in the+4oxidation state.

  1. To measure the total oxidizing power of chromium in the material, a crystal was dissolved in 2.9MHCLO4 at 100°C, cooled to 20°C , and titrated with standard Fe2+ , using Pt and Ag - AgCl electrodes to find the end point. Chromium above the 3 + state should oxidize an equivalent amount of Fe2+ in this step. That is,Cr4+would consume one Fe2+ , and Cr6+in Cr2O72- would consume three Fe2+ :

role="math" localid="1664873864085" Cr4++Fe2+Cr3++Fe3+12Cr2O72-+3Fe2+Cr3++3Fe3+

2. In a second step, the total chromium content was measured by dissolving a crystal in 2.9MHCLO4 at and cooling to 20°C . Excess and were then added to oxidize all chromium to Cr2O72- . Unreacted S2O8-2was destroyed by boiling, and the remaining solution was titrated with standard Fe2+ . In this step, each Crin the original unknown reacts with three Fe2+ .

Crx++S2O82-Cr2O72-12Cr2O72-+3Fe2+Cr3++3Fe3+

In Step 1,0.4375g of laser crystal required 0.498mL of (prepared by dissolving in ). In step , of crystal required of the same solution. Find the average oxidation number of in the crystal and find the total micrograms ofpre gram of crystal.

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