Chapter 16: Q10P (page 391)
What is a Jones reductor and what is it used for?
Short Answer
Jones reductor is a reducing substance that can be used to lower the oxidation state of a metal ion in an aqueous solution
Chapter 16: Q10P (page 391)
What is a Jones reductor and what is it used for?
Jones reductor is a reducing substance that can be used to lower the oxidation state of a metal ion in an aqueous solution
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Get started for freeis an anode for lithium batteries. Cobalt is present as a mixture of Co (III) and Co (II). Most preparations also contain inert lithium salts and moisture. To find the stoichiometry, Co was measured by atomic absorption and its average oxidation state was measured by a potentiometric tritration.39 For the titration, 25.00mg of solid were dissolved under in 5. mL containing
in plusto give a clear pink solution:
Unreacted required 3.228 mL of for complete titration.
(a) How many mmol of are contained in 25.00mg of the material?
(b) Atomic absorption found 56.4 wt% Co in the solid. What is the average oxidation state of Co ?
(c) Find y in the formula .
(d) What is the theoretical quotient wt\% Li/wt\% Co in the solid? The observed quotient, after washing away inert lithium salts, wasIs the observed quotient consistent with the average cobalt oxidation state?
The pathogenic bacterium Salmonella enterica uses tetrathionate found in the human gut as an oxidant- just as we useto metabolize our food. Write the half-reaction in which tetrathionate serves as an oxidant. Is tetrathionate as powerful an oxidant as?
Aqueous glycerol solution weighing 100.0m gwas treated with 50.0 mL of 0.083 7 M in 4 MHCIat for15minto oxidize glycerol to formic acid.
Glycerol Formic acid
FM92.095
The excess required 12.11mL of 0.044 8 MFto reach a ferroin end point. Find wt%glycerol in the unknown.
A titration of 50.0 mLof unknown with 0.100MCeat , monitored with Pt and calomel electrodes, gave data in the table. Prepare a Gran plot and decide which data lie on a straight line. Find the x-intercept of this line, which is the equivalence volume. Calculate the molarity of in the unknown.
Calcium fluorapatitelaser crystals were doped with chromium to improve their efficiency. It was suspected that the chromium could be in theoxidation state.
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2. In a second step, the total chromium content was measured by dissolving a crystal in at and cooling to . Excess and were then added to oxidize all chromium to . Unreacted was destroyed by boiling, and the remaining solution was titrated with standard . In this step, each Crin the original unknown reacts with three .
In Step 1,0.4375g of laser crystal required 0.498mL of (prepared by dissolving in ). In step , of crystal required of the same solution. Find the average oxidation number of in the crystal and find the total micrograms ofpre gram of crystal.
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