What mass of sample in Figure 28-3 is expected to give a sampling standard deviation of \( \pm 6\% \)?

Short Answer

Expert verified

The mass of the sample which produces the relative standard deviation of \(1\% \)

Step by step solution

01

Definition of Standard deviation.

  • The standard deviation is a measure of how far something deviates from the mean (for example, spread, dispersion, or spread). A "typical" variation from the mean is represented by the standard deviation.
  • Because it returns to the data set's original units of measurement, it's a common measure of variability.
  • The standard deviation, defined as the square root of the variance, is a statistic that represents the dispersion of a dataset relative to its mean.
02

Determine the Sampling Standard deviation.

In this task we will calculate the mass of sample in Figure \(28 - 3\) expected to give a sampling standard deviation of\( \pm 6\% \).

Here we will use the equation \(28 - 5\) for relative variance\(\left( {{R^2}} \right)\) :

\(\begin{array}{l}{R^2} = {\left( {\frac{{{\delta _n}}}{n}} \right)^2}\\ = \frac{{pq}}{n}n\\{R^2} = pq\end{array}\)

Where, \(p\) and \(q\) are the fraction of particles present

Next we will rearrange the equation \(28 - 5\)to the following and calculate the mass of sample:

\(\begin{array}{l}m{R^2} = {K_a}\\m = \frac{{{K_a}}}{{{R^2}}}\\m = \frac{{36\;{\rm{g}}}}{{{6^2}}}\\m = 1\;{\rm{g}}\end{array}\)

Where, \(R\) is the relative standard deviation and \({K_a}\) is the sampling constant

Therefore, the mass of the sample which produces the relative standard deviation of \(1\% \)

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with Vaia!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

Explain how to prepare a powder with an average particle diameter near \(100\mu m\) by using sieves from Table 28-2. How would such a particle mesh size be designated?

From their standard reduction potentials, which of the following metals would you expect to dissolve in \({\rm{HCl}}\)by the reaction\({\rm{M}} + n{{\rm{H}}^ + } \to {{\rm{M}}^{n + }} + \frac{n}{2}{{\rm{H}}_2}:{\rm{Zn}},{\rm{Fe}},{\rm{Co}},{\rm{Al}},{\rm{Hg}},{\rm{Cu}},{\rm{Pt}}\),\({\bf{Au}}\)?

(When the potential predicts that the element will not dissolve, it probably will not. If it is expected to dissolve, it may dissolve if some other process does not interfere. Predictions based on standard reduction potentials at \({\bf{2}}{{\bf{5}}^{^{\bf{o}}}}C\) are only tentative, because the potentials and activities in hot, concentrated solutions vary widely from those in the table of standard potentials.)

In analyzing a lot with random sample variation, you find a sampling standard deviation of \({\bf{65}}\% .\)Assuming negligible error in the analytical procedure, how many samples must be analyzed to give \(9{\bf{5}}\% \)confidence that the error in the mean is within\(64\% \)of the true value? Answer the same question for a confidence level of \(90\% \).

An example of a mixture of 1-mm-diameter particles of \({\rm{KCl}}\)and \({\rm{KN}}{{\rm{O}}_3}\)in a number ratio \(1:99\)follows Equation 28-4. A sample containing \({10^4}\)particles weighs\(11.0\;{\rm{g}}\). What is the expected number and relative standard deviation of \({\rm{KCl}}\)particles in a sample weighing\(11.0 \times {10^2}\;{\rm{g}}\)?

Why is it advantageous to use large particles \(\left( {{\bf{50}}{\rm{ }}\mu {\bf{m}}} \right)\) for solid phase extraction, but small particles \(\left( {{\bf{5}}{\rm{ }}\mu {\bf{m}}} \right)\) for chromatography?

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.

Sign-up for free