In analyzing a lot with random sample variation, you find a sampling standard deviation of \({\bf{65}}\% .\)Assuming negligible error in the analytical procedure, how many samples must be analyzed to give \(9{\bf{5}}\% \)confidence that the error in the mean is within\(64\% \)of the true value? Answer the same question for a confidence level of \(90\% \).

Short Answer

Expert verified

The samples in \(95\% \) Confidence is \(n = 6,10.3,8\) and the samples in \(90\% \) Confidence is\(n = 6,6,5.25\).

Step by step solution

01

Definition of Standard deviation.

  • The standard deviation is a measure of how far something deviates from the mean (for example, spread, dispersion, or spread). A "typical" variation from the mean is represented by the standard deviation.
  • Because it returns to the data set's original units of measurement, it's a common measure of variability.
  • The standard deviation, defined as the square root of the variance, is a statistic that represents the dispersion of a dataset relative to its mean.
02

Determine the samples in \(95\% \)confidence.

In this task we have a sampling standard deviation of \(65\% \). We will calculate the number of samples that must be analyzed in order to give \(95\% \) and \(90\% \) confidence that the error in the mean is within \( \pm 4\% \) of the true value.

\(95\% \)Confidence

Here we will use the equation \(28 - 7\) where \({s_s} = 0.05\)and \(e = 0.04\) :

\(\begin{aligned}{}n &= \frac{{{t^2}s_s^2}}{{{e^2}}}\\n &= \frac{{{{1.960}^2} \times {{0.05}^2}}}{{{{0.04}^2}}}\\n &= 6\end{aligned}\)

For \(n = 6.\) there are \({5^\circ }\) of freedom so \(t = 2.571\) which would give us the following value of \(n\) :

\(\begin{aligned}{}n &= \frac{{{t^2}s_8^2}}{{{e^2}}}\\n &= \frac{{{{2.571}^2} \times {{0.05}^2}}}{{{{0.04}^2}}}\end{aligned}\)

\(n = 10.3\)

For \(n = 10.3\) there are \({9^\circ }\) of freedom so \(t = 2.262\) which would give us the following value of \(n\) :

\(\begin{aligned}{}n& = \frac{{{t^2}s_s^2}}{{{e^2}}}\\n &= \frac{{{{2.262}^2} \times {{0.05}^2}}}{{{{0.04}^2}}}\\n &= 8\end{aligned}\)

03

Determine the samples in \(90\% \)confidence.

Find that for \(t = 2.365\) the \(n = 8.74\) so in this case we would use a total of \(8\) samples

\(90\% \)Confidence:

Here we will also use the equation 28-7 where \({s_s} = 0.05\)and \(e = 0.04\) :

\(\begin{aligned}{}n&= \frac{{{t^2}s_s^2}}{{{e^2}}}\\n &= \frac{{{{1.645}^2} \times {{0.05}^2}}}{{{{0.04}^2}}}\\n &= 6\end{aligned}\)

For \(n = 6\) there are \({5^\circ }\) of freedom so \(t = 2.015\) which would give us the following value of \(n\) :

\(\begin{aligned}{}n &= \frac{{{t^2}s_s^2}}{{{e^2}}}\\n &= \frac{{{{2.015}^2} \times {{0.05}^2}}}{{{{0.04}^2}}}\\n &= 6\end{aligned}\)

When,\(t = 1.833\)then \(n = 5.25\),so in this case we would use a total of \(6\)samples.

Therefore, the samples in \(95\% \) Confidence is \(n = 6,10.3,8\) and the samples in \(90\% \) Confidence is\(n = 6,6,5.25\).

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Most popular questions from this chapter

To pre-concentrate cocaine and benzoylecgonine from river water described at the opening of this chapter, solid-phase extraction was carried out at \({\rm{pH}}\,\,2\) using the mixed-mode cation-exchange resin in Figure 28-19. After passing \(500\;{\rm{mL}}\)of river water through \(60{\rm{mg}}\)of resin, the retained analytes were eluted first with \(2\;{\rm{mL}}\)of \({\rm{C}}{{\rm{H}}_3}{\rm{OH}}\)and then with \(2\;\,\,{\rm{mL }}of\,\,\,2\% \) ammonia solution in\({\rm{C}}{{\rm{H}}_3}{\rm{OH}}\). Explain the purpose of using \({\rm{pH}}2\) for retention and dilute ammonia for elution.

In an experiment analogous to that in Figure 28-3, the sampling constant is found to be \({K_{\rm{s}}} = 20\;{\rm{g}}.\)

(a) What mass of sample is required for a \( \pm 2\% \)sampling standard deviation?

(b) How many samples of the size in part (a) are required to produce \(90\% \)confidence that the mean is known to within\(1.5\% \)?

By what factor must the mass increase to reduce the sampling standard deviation by a factor of 2?

Many metals in seawater can be preconcentrated for analysis by coprecipitation with\({\rm{Ga}}{({\rm{OH}})_3}\). A \(200 - \mu {\rm{L}}\)HCl solution containing \(50\mu {\rm{g}}\)of \({\rm{G}}{{\rm{a}}^{3 + }}\)is added to \(10.00\;{\rm{mL}}\) of the seawater. When the \({\rm{pH}}\)is brought to \(9.1\)with\({\rm{NaOH}}\), a jellylike precipitate forms. After centrifugation to pack the precipitate, the water is removed and the gel is washed with water. Then the gel is dissolved in \(50\mu {\rm{L}}\) of \({\rm{HN}}{{\rm{O}}_3}\)and aspirated into an inductively coupled plasma for atomic emission analysis. The preconcentration factor is\(10\;{\rm{mL}}/50\mu {\rm{L}} = 200\). The figure shows elemental concentrations in filtered and unfiltered seawater as a function of depth near hydrothermal vents.

(a) What is the atomic ratio (Ga added): (Ni in seawater) for the sample with the highest concentration of\({\rm{Ni}}\)?

(b) The results given by gray lines were obtained with seawater samples that were not filtered prior to coprecipitation. Colored lines are from filtered samples. Results for Ni do not vary between the two procedures, but results for Fe vary. Explain what this means.

(a) Explain how dispersive liquid-liquid microextraction reduces the use of solvent in comparison with liquid-liquid extraction.

(b) What is the purpose of the disperser solvent, which is used in much greater volume than the extraction solvent?

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