Chapter 20: Q17P (page 526)
Light passes from benzene (medium1)to water (medium 2) in Figure 20at (a)or (b). Find the anglein each case.
Short Answer
a) For,
b) For ,.
Chapter 20: Q17P (page 526)
Light passes from benzene (medium1)to water (medium 2) in Figure 20at (a)or (b). Find the anglein each case.
a) For,
b) For ,.
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Get started for freeThe photograph of upconversion in Color Plate 21shows total internal reflection of the blue ray inside the cuvet. The angle of incidence of the blue ray on the wall of the cuvet is. We estimate that the refractive index of the organic solvent is 1.50and the refractive index of the fused-silicacuvet is 1.46. Calculate the critical angle for total internal reflection at the solvent/ silica interface and at the silica/air interface. From your calculation, which interface is responsible for total internal reflection in the photo?
Show that a grating with 103 grooves/cm provides a dispersion of 5.88 per mm of wavelength if n 5 1 and f 5 108 in Equation 20-4.
(a) The true absorbance of a sample is 1.500, but stray light reaches the detector. Find the apparent transmittance and apparent absorbance of the sample. (b) How much stray light can be tolerated if the absorbance error is not to exceedat a true absorbance of? (c) A research-quality spectrophotometer has a stray light level of ,at. What will be the maximum absorbance error for a sample with a true absorbance of 2? Of 3?
Explain how beam chopping reduces line noise and noise from source drift.
The variation of refractive index, n, with wavelength for fused silica is given by
where is expressed in .
(a) Make a graph of n versus with points at the following wavelengths: 0.2,0.4,0.6,0.8,1,2,3,4,5, and .
(b) The ability of a prism to spread apart (disperse) neighboring wavelengths increases as the slope increases. Is the dispersion of fused silica greater for blue light or red light?
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