Chapter 20: Q2P (page 525)
Explain how a laser generates light. List important properties of laser light.
Short Answer
The laser is based on quantum phenomena in the transmission of energy by radiation.
Chapter 20: Q2P (page 525)
Explain how a laser generates light. List important properties of laser light.
The laser is based on quantum phenomena in the transmission of energy by radiation.
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Get started for freeThe photograph of upconversion in Color Plate 21shows total internal reflection of the blue ray inside the cuvet. The angle of incidence of the blue ray on the wall of the cuvet is. We estimate that the refractive index of the organic solvent is 1.50and the refractive index of the fused-silicacuvet is 1.46. Calculate the critical angle for total internal reflection at the solvent/ silica interface and at the silica/air interface. From your calculation, which interface is responsible for total internal reflection in the photo?
In Figure 20-35, the relative detection limit is 37 after 1sof signal averaging, 12.5 after 10s, and 5.6 after 40 sof signal averaging. Based on the value of 37 at 1 s, what are the expected detection limits at 10 sand 40 sin an ideal experiment?
Refer to the Fourier transform infrared spectrum in Figure 20-33.
(a) The interferogram was sampled at retardation intervals of. What is the theoretical wavenumber range (0 to ?) of the
spectrum?
(b) A total of 4 096 data points were collected from . Compute the value of, the maximum retardation.
(c) Calculate the approximate resolution of the spectrum.
(d) The interferometer mirror velocity is given in the figure caption. How many microseconds elapse between each datum?
(e) How many seconds were required to record each interfero gram once?
(f) What kind of beam splitter is typically used for the region 400 to 4 000? Why is the region below 400not observed?
The true absorbance of a sample is 1.000, but the mono chromator passes 1.0% stray light. Add the light coming through the sample to the stray light to find the apparent transmittance of the sample. Convert this answer back into absorbance and find the relative error in the calculated concentration of the sample.
The true absorbance of a sample is 1.000, but the mono chromator passes 1.0% stray light. Add the light coming through the sample to the stray light to find the apparent transmittance of the sample. Convert this answer back into absorbance and find the relative error in the calculated concentration of the sample.
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