Hydrocarbons in the cab of an automobile were measured during trips on the New Jersey Turnpike and trips through the Lincoln Tunnel connecting New York and New Jersey. The concentrations ( ±standard deviations) ofm- andp -xylene were

Turnpike:31.4±30.0μg/m3(32measurements)Tunnel:52.9±29.8μg/m3(32measurements)

Do these results differ at the 95%confidence level? At the 99%confidence level?

Short Answer

Expert verified

The analyses done from the New Jersey Turnpike through the Lincoln Tunnel at 95% and 99% confidence intervals differ significantly in terms of their means but not significantly in terms of their standard deviations and variances.

Step by step solution

01

Perform F test

For comparing two different locations of analysis, use both the test and the test.

The F-test is done as shown below.

Fcalc=s12s22=30.0229.82=1.01.

Ftable(95%CL)1.84.

Ftable(99%CL)2.35.

Since Fcalc<Ftableat both 95% and 99% confidence levels, there is no significant difference between the variances and the standard deviations of the analysis done in two different locations at both confidence levels.

02

Perform t test

The t-test is done as shown below.

The conclusion in our F test result states that Fcalc<Ftable at both confidence levels. Now, perform a case 2a of the -test.

spooled=s12n1-1+s22n2-1n1+n2-nt=30.0232-1+29.8232-132+32-2=29.90016722

tcalc=x1-x2spooledn1n2n1+n2=31.4-52.929.90016722323232+32=2.88

ttable(95%CL)2.042.ttable(99%CL)2.750.

Since tcalc>ttableat both 95% and 99% confidence levels, there is a significant difference between the means of the analysis done in two different locations at both confidence levels.

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Most popular questions from this chapter

Which statement about the F test is true? Explain your answer.

(i) IfFcalculated<Ftable, there is more than a 5%chance that the two sets of data are drawn from populations with the same population standard deviation.

(ii) IfFcalculated<Ftable, there is at least 95%probability that the two sets of data are drawn from populations with the same population standard deviation.

Here is a least-squares problem that you can do by hand with a calculator. Find the slope and intercept and their standard deviations for the straight line drawn through the points(x,y)=(0,1),(2,2)and (3,3). Make a graph showing the three points and the line. Place error bars (±sy)on the points.

Here are mass spectrometric signals for methane inH2:

CH4(vol%):00.0620.1220.2450.4860.9711.921Signal(mV):9.147.595.6193.8387.5812.51671.9

(a) Subtract the blank value (9.1) from all other values. Then use the method of least squares to find the slope and intercept and their uncertainties. Construct a calibration curve.

(b) Replicate measurements of an unknown gave 152.1, 154.9, 153.9 and 155.1mV , and a blank gave 8.2,9.4,10.6 and 7.8mV . Subtract the average blank from the average unknown to find the average corrected signal for the unknown.

(c) Find the concentration of the unknown, its standard uncertainty (ux) , and the95%confidence interval.

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(a) Make a graph of log (current) versus log( concentration). Over what range is the log-log calibration linear?

(b)FindtheequationoftheLine

InTheform log(current)=m×log(concentration)+b

(c) Find the concentration of p-nitrophenol corresponding to a signal of 99.9nA.

(d) Propagation of uncertainty with logarithm. For a signal of 99.9nA, log (concentration) and its standard uncertainty turn out to be 0.68315±0.04522. With rules for propagation of uncertainty from Chapter 3, find the uncertainty in concentration.

Traces of toxic, man-made hexachlorohexanes in North Sea sediments were extracted by a known process and by two new procedures, and measured by chromatography.

(a) Is the concentration parts per million, parts per billion, or something else?

(b) Is the standard deviation for procedure B significantly different from that of the conventional procedure?

(c) Is the mean concentration found by procedure B significantly different from that of the conventional procedure?

(d) Answer the same two questions as parts (b) and (c) to compare procedure A to the conventional procedure.

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