A straight line is drawn through the points (3.0,-3.87×104),(10.0,-12.99×104),(20.0,-25.93×104),(30.0,-38.89×104), and (40.0,-51.96×104) to give m=-1.29872×104, b=256.695,um=13.190,ub=323.57, and sy=392.9. Express the slope and intercept and their uncertainties with reasonable significant figures.

Short Answer

Expert verified

The slope and its uncertainty with a reasonable number of significant figures is -1.298(±0.001)×104.

The intercept and its uncertainty with a reasonable number of significant figures is3(±3)×102.

Step by step solution

01

The standard deviation and uncertainty of slope and intercept

The standard deviation of y:sy:

The standard deviation of y is mathematically represented as

σysy=(di2)n-2

The standard uncertainty of a slope and an intercept:

The standard uncertainty of a slope is mathematically presented asum2=sy2nD

The standard uncertainty of an intercept is mathematically presented as ub2=sy2(xi2)D

02

The slope and their uncertainty for the given points of a straight line

Given data:

The points of the straight line are:

(3.0,-3.87×104),(10.0,-12.99×104),(20.0,-25.93×104),(30.0,-38.89×104),and(40.0,-51.96×104).

The slopem=-1.29872×104

The intercept b=256.695

The uncertainty in the slopeum=13.190

The uncertainty in the intercept ub=323.57

The standard deviation of Y is sy=392.9

The slope with its uncertainty is written as:

slope =-1.29872×104(±0.0013190×104).

=-1.2987(±0.0013)×104(The subscript digits are insignificant figures)

=-1.299(±0.001)×104(The corrected significant figure).

03

The intercept and their uncertainty for given points of a straight line

The intercept with its uncertainty is written as:

intercept=256.695(±323.57)

=3(±3)×102(The corrected significant figure).

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Most popular questions from this chapter

(a) The linear calibration curve in Figure 4-13 isy=0.01630(±0.00022)x+0.0047(±0.0026)withsy=0.0059. Find the quantity of unknown protein that gives a measured absorbance of when a blank has an absorbance of 0.095

(b) Figure 4-13 has n=14 calibration points in the linear portion. You measure k=14replicate samples of unknown and find a mean corrected absorbance of 0.169 Find the standard uncertainty and 95%confidence interval for protein in the unknown.

Spreadsheet for standard deviation. Let's create a spreadsheet to compute the mean and standard deviation of a column of numbers in two different ways. The spreadsheet here is a template for this exercise.

(a) Reproduce the template on your spreadsheet. Cells B4to B8contain the data ( xvalues) whose mean and standard deviation we will compute.

(b) Write a formula in cell B9to compute the sum of numbers in B4to B8.

(c) Write a formula in cell B10to compute the mean value.

(d) Write a formula in cell C4to compute (- mean), where xis in cellB4 and the mean is in cell B10. Use Fill Down to compute values in cells C5to C8.

(e) Write a formula in cellto compute the square of the value in cell. Use Fill Down to compute values in cellsto.

(f) Write a formula in cell D9 to compute the sum of the numbers in cells D4to D8.

(g) Write a formula in cell B11to compute the standard deviation.

(h) Use cells B13to B18to document your formulas.

(i) Now we are going to simplify life by using formulas built into the spreadsheet. In cell B21type ''=SUM(B4:B8)''which means find the sum of numbers in cells B4to B8. Cell B21should display the same number as cell B9. In general, you will not know what functions are available and how to write them. In Excel 2010, use the Formulas ribbon and Insert Function to find SUM.

(j) Select cellB22. Go to Insert Function and find AVERAGE. When you type "=AVERAGE(B4:B8)" in cell B22, its value should be the same asB10.

(k) For cellB23, find the standard deviation function(=STDEVB4:B8n)and check that the value agrees with cell B11.

Which statement about the F test is true? Explain your answer.

(i) IfFcalculated<Ftable, there is more than a 5%chance that the two sets of data are drawn from populations with the same population standard deviation.

(ii) IfFcalculated<Ftable, there is at least 95%probability that the two sets of data are drawn from populations with the same population standard deviation.

A Standard Reference Material is certified to contain 94.6 ppm of an organic contaminant in soil. Your analysis gives values of 98.6,98.4,97.2,94.6, and 96.2ppm. Do your results differ from the expected result at the 95% confidence level? If you made one more measurement and found 94.5, would your conclusion change?

Nitrite(NO2-)was measured by two methods in rainwater and unchlorinated drinking water. The results±standard deviation (number of samples) are

SOURCE. Data from I. Sarudi and I. Nagy, Talanta 1995,42,1099

(a) Do the two methods agree with each other at theconfidence level for both rainwater and drinking water?

(b) For each method, does the drinking water contain significantly more nitrite than the rainwater (at the 95%confidence level)?

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