Chapter 14: Problem 62
The volume of this HCP unit cell is (A) \(24 \sqrt{2} r^{3}\) (B) \(16 \sqrt{2} r^{3}\) (C) \(12 \sqrt{2} r^{3}\) (D) \(\frac{64}{3 \sqrt{3}} r^{3}\)
Short Answer
Expert verified
The volume of the HCP unit cell is (D) \(\frac{64}{3 \root{3}} r^{3}\).
Step by step solution
01
Understand the HCP Structure
The Hexagonal Close-Packed (HCP) structure is constituted of a hexagonal lattice. It has a characteristic arrangement of atoms with two layers where the atoms of the second layer fit into the gaps of the first layer. Each HCP unit cell has 12 atoms at the corners of the hexagon, 2 atoms at the hexagon faces, and 3 atoms between the hexagonal layers.
02
Calculate the Volume of the HCP Unit Cell
The volume of a HCP unit cell can be calculated using the formula for the volume of the hexagonal prism: \( V = \frac{3\root{3}}{2}a^{2} \times h \), where \(a\) is the side of the hexagon and \(h\) is the height of the hexagonal prism. For HCP, \(a = 2r\) and \(h = \frac{4}{\root{3}}r\), where \(r\) is the atomic radius. Substituting these values into the formula, we get \( V = \frac{3\root{3}}{2} (2r)^{2} \times \frac{4}{\root{3}}r = \frac{64}{3\root{3}} r^{3} \).
03
Choose the Correct Option
Comparing the calculated volume of the unit cell with the options given, the correct option is (D) \( \frac{64}{3\root{3}} r^{3} \).
Unlock Step-by-Step Solutions & Ace Your Exams!
-
Full Textbook Solutions
Get detailed explanations and key concepts
-
Unlimited Al creation
Al flashcards, explanations, exams and more...
-
Ads-free access
To over 500 millions flashcards
-
Money-back guarantee
We refund you if you fail your exam.
Over 30 million students worldwide already upgrade their learning with Vaia!
Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Hexagonal Close-Packed structure
In the field of crystallography, the Hexagonal Close-Packed (HCP) structure is a unique arrangement of atoms that optimizes space utilization within the crystal lattice. The geometry entails a layered approach, with each layer staggered so that the atoms of one layer fit in the troughs of the adjacent layer, facilitating a dense packing.
Understanding Layers and Coordination
Importantly, this structure possesses an ABAB layer stacking sequence, with each atom touching three in the layer below and three in the layer above, optimizing spatial efficiency. This results in a typical coordination number of 12, indicating each atom is in direct contact with 12 others.Importance in Materials Science
Materials exhibiting this crystalline structure, like magnesium and titanium, tend to have high tensile strength and resistance to deformation. Grasping the concept of the HCP structure is crucial for those delving into the material sciences and physics, particularly for applications requiring materials that can withstand strong forces without occupying excessive volume.Volume calculation of hexagonal prism
Crucial for students and professionals in crystallography and materials science, the volume of a hexagonal prism - the shape forming the basis of an HCP unit cell - is determined using a specific mathematical formula.
Formula and Application
One can calculate it by the formula: \( V = \frac{3\sqrt{3}}{2}a^2 \times h \), where \(a\) represents the edge length of the hexagon's base, and \(h\) denotes the prism's height. When wielded correctly, this formula provides insight into the actual volume occupied by atoms within the HCP structure.Significance in Crystal Studies
Understanding this calculation is imperative not only for academic exercises, such as those found in JEE Advanced Physics examinations but also for real-world applications in designing materials with specific volumetric requirements and in predicting the properties of materials based on the space they occupy.Atomic radius in crystal structures
The atomic radius plays a pivotal role in understanding and modeling crystal structures. In essence, it is the measure from the center of an atom to the outer boundary of its electron cloud.
Role in Volume Calculations
Within a crystal lattice, the atomic radius influences the spacing between atoms and ultimately dictates the lattice's dimensions. In hexagonal close-packed structures, the relationship between the atomic radius and lattice dimensions is direct and can simplify the calculation of the cell's volume.Significance in Material Properties
Furthermore, the atomic radius affects physical properties, such as density and thermal expansion. In educational contexts, like the JEE Advanced Physics curriculum, comprehending how the atomic radius impacts both the micro (atomic level) and macro (material properties) scales is of utmost importance, leading to better material selection and engineering decisions in real-world applications.JEE Advanced Physics
The Joint Entrance Examination (JEE) Advanced level is a highly competitive examination in India that paves the way for admission to prestigious engineering institutes. Physics is a core subject of this examination, demanding a strong grasp of concepts like crystallography, solid-state physics, and material science.