Each molecule of a gas has \(\mathrm{f}\) degrees of freedom. The radio \(\left(\mathrm{C}_{\mathrm{p}} / \mathrm{C}_{\mathrm{v}}\right)=\gamma\) for the gas is (A) \(1+(\mathrm{f} / 2)\) (B) \(1+(1 / \mathrm{f})\) (C) \(1+(2 / \mathrm{f})\) (D) \(1+\\{(\mathrm{f}-1) / 3\\}\)

Short Answer

Expert verified
The correct option for the ratio \(\left(\mathrm{C}_{\mathrm{p}} / \mathrm{C}_{\mathrm{v}}\right)=\gamma\) for the gas is (C) \(1+(2 / \mathrm{f})\).

Step by step solution

01

Relationship between specific heat capacities and degrees of freedom

To find the relationship between the specific heat capacities and the degrees of freedom (\(f\)), we can recall that: \(C_p=C_v+nR\) Where \(C_p\) = specific heat capacity at constant pressure, \(C_v\) = specific heat capacity at constant volume, \(n\) = number of moles, and \(R\) = ideal gas constant.
02

Equation of specific heat capacity at constant volume

For a gas with \(f\) degrees of freedom, the specific heat capacity at constant volume (\(C_v\)) is given by: \(C_v=\frac{f}{2}nR\) We are going to use this equation to express \(\frac{C_p}{C_v}\) in terms of \(f\).
03

Derive the expression for gamma (\(\gamma\))

To find the ratio \(\gamma\), we can substitute the expression of \(C_v\) (from step 2) into the equation from step 1: \(C_p - C_v = nR\) Then divide both sides by \(C_v\): \(\frac{C_p}{C_v}-1 = \frac{2}{f}\) Add 1 on both sides of the equation to get the ratio: \(\frac{C_p}{C_v} = \gamma = 1 + \frac{2}{f}\) Comparing our derived expression with the given options, we find that it matches with option (C).
04

Answer

The correct option for the ratio \(\left(\mathrm{C}_{\mathrm{p}} / \mathrm{C}_{\mathrm{v}}\right)=\gamma\) for the gas is (C) \(1+(2 / \mathrm{f})\)

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