70 calorie of heat are required to raise the temperature of 2 mole of an ideal gas at constant pressure from \(30^{\circ} \mathrm{C}\) to $35^{\circ} \mathrm{C}$ The amount of heat required to raise the temperature of the same gas through the same range at constant volume is $\ldots \ldots \ldots \ldots \ldots .$ calorie. (A) 50 (B) 30 (C) 70 (D) 90

Short Answer

Expert verified
The heat required to raise the temperature of the same gas through the same range at constant volume is approximately 50 calories. The correct answer is (A) 50.

Step by step solution

01

Identify the given information

We are given that 70 calories of heat are required to raise the temperature of 2 moles of an ideal gas from \(30^{\circ} \mathrm{C}\) to \(35^{\circ} \mathrm{C}\) at constant pressure. Also, we need to find the heat required to raise the temperature of the gas through the same range at constant volume.
02

Use the heat formula at constant pressure

We can use the formula for heat at constant pressure: \[Q_p = nC_p \Delta T\] where \(Q_p\) is the heat at constant pressure, \(n\) is the number of moles, \(C_p\) is the specific heat capacity at constant pressure, and \(\Delta T\) is the change in temperature.
03

Calculate the specific heat capacity at constant pressure

We can plug in the given values and solve for \(C_p\): \[70 \text{ cal} = 2 \text{ moles} \cdot C_p \cdot (35^{\circ} \mathrm{C} - 30^{\circ} \mathrm{C})\] First, calculate the change in temperature: \(\Delta T = 35^{\circ} \mathrm{C} - 30^{\circ} \mathrm{C} = 5^{\circ} \mathrm{C}\) Now, plug it into the equation to find \(C_p\): \[C_p = \frac{70 \text{ cal}}{2 \text{ moles} \cdot 5^{\circ} \mathrm{C}} = 7 \frac{\text{cal}}{\text{mole}\cdot ^{\circ} \mathrm{C}}\]
04

Find the specific heat capacity at constant volume

For an ideal gas, the relationship between specific heat capacities at constant pressure and constant volume is: \[C_p - C_v = R\] where \(R\) is the gas constant. For this problem, we can use the value of \(R = 1.987 \frac{\text{cal}}{\text{mole}\cdot ^{\circ} \mathrm{C}}\). Now, we can find \(C_v\): \[C_v = C_p - R = 7 \frac{\text{cal}}{\text{mole}\cdot ^{\circ} \mathrm{C}} - 1.987 \frac{\text{cal}}{\text{mole}\cdot ^{\circ} \mathrm{C}} = 5.013 \frac{\text{cal}}{\text{mole}\cdot ^{\circ} \mathrm{C}}\]
05

Calculate the heat at constant volume

Now that we have \(C_v\), we can calculate the heat at constant volume using the formula: \[Q_v = nC_v \Delta T\] Plug in the values: \[Q_v = 2 \text{ moles} \cdot 5.013 \frac{\text{cal}}{\text{mole}\cdot ^{\circ} \mathrm{C}} \cdot 5^{\circ} \mathrm{C}\] Calculate the heat at constant volume: \[Q_v = 50.13 \text{ cal}\] Since the given options are all integers, we can round the answer to the nearest integer: \[Q_v \approx 50 \text{ cal}\] So, the heat required to raise the temperature of the same gas through the same range at constant volume is approximately 50 calories. The correct answer is (A) 50.

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