If a quantity of heat \(1163.4 \mathrm{~J}\) is supplied to one mole of nitrogen gas, at room temperature at constant pressure, then the rise in temperature is \(\mathrm{R}=8.31\\{\mathrm{~J} /(\mathrm{m} \cdot 1 . \mathrm{k})\\}\) (A) \(28 \mathrm{~K}\) (B) \(65 \mathrm{~K}\) (C) \(54 \mathrm{~K}\) (D) \(40 \mathrm{~K}\)

Short Answer

Expert verified
The rise in temperature when a quantity of heat (1163.4 J) is supplied to one mole of nitrogen gas at room temperature at constant pressure is approximately 40 K. Therefore, the correct option is (D) \(40\,\mathrm{K}\).

Step by step solution

01

Write down the formula for heat capacity at constant pressure

We will use the formula for heat capacity at constant pressure (Cp) for an ideal gas: \[ q = nC_p∆T \] where q = heat supplied (1163.4 J), n = number of moles (1 mole), Cp = heat capacity at constant pressure, ∆T = rise in temperature.
02

Determine the heat capacity at constant pressure for nitrogen gas

For diatomic molecules like nitrogen gas, the molar heat capacity at constant pressure (Cp) can be calculated by adding the gas constant R to the molar heat capacity at constant volume (Cv), which would result in the equation: \[ C_p = C_v + R \] For a diatomic molecule, the molar heat capacity at constant volume (Cv) is given by the equation: \[ C_v = \dfrac{5}{2} R \] Substitute the value of Cv in Cp formula: \[ C_p = \dfrac{5}{2} R + R \]
03

Calculate Cp using the given value of R

Now, substitute the given value of R in the Cp formula: \[ C_p = \dfrac{5}{2}(8.31) + (8.31) \] \[ C_p = 20.775 + 8.31 = 29.085 \, \mathrm{J/(mol.K)} \]
04

Solve for the rise in temperature (∆T)

Now, we have all the necessary values to find the rise in temperature (∆T). The formula that we will use is: \[ ∆T = \dfrac{q}{nC_p} \] Substitute the given values: \[ ∆T = \dfrac{1163.4 \,\mathrm{J}}{1\,\mathrm{mol} \times 29.085\, \mathrm{J/(mol.K)}} \]
05

Calculate the final answer

Calculate the final value of the rise in temperature: \[ ∆T = \dfrac{1163.4}{29.085} = 39.96 \approx 40\,\mathrm{K} \] The rise in temperature when a quantity of heat (1163.4 J) is supplied to one mole of nitrogen gas at room temperature at constant pressure is approximately 40 K. Therefore, the correct option is (D) \(40\,\mathrm{K}\).

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