Chapter 15: Problem 1
Set up two process schemes for the production of ethanol from wood, one based on a thermochemical platform and the other based on a biochemical platform. What are advantages and disadvantages of both schemes?
Chapter 15: Problem 1
Set up two process schemes for the production of ethanol from wood, one based on a thermochemical platform and the other based on a biochemical platform. What are advantages and disadvantages of both schemes?
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A company producing cola wants to increase the production of "green bottles" made of PET (polyethylene terephthalate). Therefore, they plan to build a plant to produce ethylene glycol (one of the two monomers of PET) from sugarcane residues (bagasse). The capacity will be \(500 \mathrm{kt}\).year \({ }^{-1}\). a. Make a block process diagram of how this biorefinery could look like. b. Give the main reactions taking place in the process leading to ethylene glycol. c. How much bagasse (kt.year \(^{-1}\) ) would be needed in this process when bagasse is assumed to consist of \(38 \mathrm{wt} \%\) cellulose \((\mathrm{db}), 27 \mathrm{wt} \%\) hemicellulose, \(20 \mathrm{wt} \%\) lignin, \(3 \mathrm{wt} \%\) proteins, \(9 \mathrm{wt} \%\) extractives (water soluble), and \(3 \mathrm{wt} \%\) ash. Consider ethanol to be an intermediate product, which is only made from the cellulose part via enzymatic hydrolysis and subsequent sugar fermentation. d. Which products can be made from the noncellulosic part of bagasse?
Sometimes, one sees the term "oleochemical-based biorefinery." What is meant by this term and can you give a few examples?
A catalytic cracking unit in an oil refinery produces the so-called amylenes that can be dehydrogenated (abstraction of hydrogen). Which product is formed? Is there a simple biomass-derived process possible to produce the same chemical?
A biorefinery process called "Biofine" has been presented in the recent past (Kamm and Kamm, 2004). It is a biomass-based process route making use of acid hydrolysis and dehydration subprocesses and esterification with ethanol to ethyl levulinate (EL) (an ester of levulinic acid and ethanol). By-products considered are power and formic acid (FA). The production of EL is \(133 \mathrm{kt}\). year \(^{-1}\). The capital cost is 150 million US\$ (consider linear depreciation in 10 years). Table \(15.8\) gives an overview of the prices of the raw materials and by-products. In addition, the water supply costs are US\$ 500,000/year. Regarding labor, there are 17 operators per shift working at a salary of US\$ \(20 / \mathrm{h}\) and two supervisors per shift working at a salary of US\$ \(24 / \mathrm{h}\). Assume an ROI of \(15 \%\). For other costs, take the guidelines given in this chapter (Table 15.6). a. Calculate the cost and return price in US $\$$ per tonne EL produced. b. What is the price in US \$ per GJ HHV? (hint: calculate the heat of combustion of EL). c. Is it possible to produce the required ethanol in the process itself? TABLE 15.8 Overview of costs, yields of by-products, and material amounts for the "Biofine"' process $$ \begin{array}{lll} \text { Raw material/utility/by-product } &{\text { Amount }} & \text { Price in US\$ } \\ \hline \text { Feedstock } & 350 \mathrm{kt} \cdot \mathrm{year}^{-1} & 40 \cdot \mathrm{t}^{-1} \\ \text { Sulfuric acid } & 3.5 \mathrm{kt} \cdot \mathrm{year}^{-1} & 100 \cdot \mathrm{t}^{-1} \\ \text { Caustic soda } & 0.5 \mathrm{kt} \cdot \mathrm{year}^{-1} & 120 \cdot \mathrm{t}^{-1} \\ \text { Ethanol } & 35 \mathrm{kt} \cdot \text { year }^{-1} & 350 \cdot \mathrm{t}^{-1} \\ \text { Hydrogen } & 0.12 \mathrm{kt} \cdot \mathrm{year}^{-1} & 1500 \cdot \mathrm{t}^{-1} \\ \text { Ash disposal } & 17.5 \mathrm{kt} \cdot \mathrm{year}^{-1} & 35 \cdot \mathrm{t}^{-1} \\ \text { Power exported } & 3.1 \mathrm{MW} & 60 \mathrm{MWh}^{-1} \\ \text { Formic acid sold } & 38.5 \mathrm{kt} \cdot \mathrm{year}^{-1} & 110 \cdot \mathrm{t}^{-1} \\ \hline \end{array} $$
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