Consider a magnetic system whose free energy, near the critical point, scales as \(\lambda^{5} g(\epsilon, B)=g\left(\lambda^{2} \epsilon, \lambda^{3} B\right)\). Compute (a) the degree of the coexistence curve, (b) the degree of the critical isotherm, (c) the critical exponent for the magnetic susceptibility, and (d) the critical exponent for the heat capacity. Do your results agree with values of the critical exponents found in experiments?

Short Answer

Expert verified
a) \(\beta = 2\), b) \(\delta = 3\), c) \(\gamma = 3/2\), d) \(\alpha =5/2\). Exponents do not match experimental values.

Step by step solution

01

Define the given scaling relation

The problem provides the scaling relation of the free energy near the critical point as follows: \( \lambda^{5} g(\epsilon, B) = g(\lambda^{2}\epsilon, \lambda^{3}B)\).
02

Analyze the coexistence curve

The coexistence curve typically deals with the relation between the order parameter and the external field at the critical point. Near the critical point, the order parameter scales as \(M\sim B^{1/\delta}\). Therefore, to find the degree of the coexistence curve (\beta), balance the exponents as \(\epsilon\) goes to zero: \[ \lambda^\beta = \lambda^2 \] From this equation, it's clear that \(\beta = 2\).
03

Determine the degree of the critical isotherm

For the critical isotherm, the scaling relation suggests an equation form for the magnetization as \(M \sim B^{1/\delta}\) where \(\delta\) is the exponent for the critical isotherm. By equating the exponents: \[ \lambda^{1/\delta} = \lambda^3 \] Solving this gives \(1/\delta = 3\Rightarrow \delta = 3\).
04

Calculate the critical exponent of the magnetic susceptibility

The critical exponent \(\gamma\) describes the divergence of the magnetic susceptibility near the critical point. Magnetic susceptibility \(\chi\) scales as \(\chi \sim \epsilon^{-\gamma}\). From the scaling relation for the free energy, equate the magnetic terms: \[ \lambda^{\gamma} = \lambda^5 - \lambda^2 = \lambda^3 \] Solving this equation gives \(\gamma = 3/2\).
05

Evaluate the critical exponent of the heat capacity

The critical exponent \(\alpha\) describes the divergence of the heat capacity \(C\) near the critical point. The term \(C\sim \epsilon^{-\alpha}\) arises from the second derivative of the free energy with respect to temperature. From the scaling relation for free energy: \[ \lambda^{\alpha} = \lambda^5 \] Isolate \(\alpha\): \(\alpha = 5/2\).
06

Compare with experimental values

Experimental values typically show the following exponents: \(\beta\approx 1/3\), \(\delta \approx 4.8\), \(\gamma \approx 1.33\), and \(\alpha\approx 0.11\). The calculated exponents \(\beta = 2\), \(\delta = 3\), \(\gamma = 3/2\), and \(\alpha=5/2\) d not match the experimental values.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Scaling Relations
Scaling relations are mathematical tools used to analyze how physical properties change near a critical point. In magnetic systems, scaling laws describe how the free energy depends on variables like temperature (\texttt{\(\epsilon\)}) and magnetic field (\texttt{B}).
In the given problem, the scaling relation is: \[ \lambda^{5} g(\epsilon, B) = g(\lambda^2 \epsilon, \lambda^3 B)\].
This means if the temperature and magnetic field are scaled by certain factors, the free energy behaves predictably.
Understanding these scaling laws helps in determining critical exponents, which quantify the behavior of physical properties near the critical point.
Each critical exponent offers insight into how a specific property varies as the system approaches the phase transition.
Coexistence Curve
The coexistence curve represents the set of points where the system can exist in two distinct phases simultaneously, such as liquid-vapor or magnetic-nonmagnetic.
In terms of magnetic systems, it relates to how magnetization (\texttt{M}) depends on temperature (\texttt{T}) near the critical point when there's no external field.
For this problem, the order parameter \texttt{M} scales with the external magnetic field \texttt{B} as \[M \sim B^{1/\delta}\].
By balancing exponents when temperature approaches its critical value, we compute the critical exponent \texttt{\beta}, which describes the shape of the coexistence curve.
We derived \texttt{\beta = 2} from the scaling relation \[\lambda^\beta = \lambda^2\].
This tells us how the magnetization changes as the temperature approaches the critical point.
Critical Isotherm
The critical isotherm describes the relationship between magnetization (\texttt{M}) and external magnetic field (\texttt{B}) precisely at the critical temperature (\texttt{T_c}).
Using the scaling relation form \[M \sim B^{1/\delta}\], we determined that at critical temperature, magnetization follows a power law behavior with \[1/\delta = 3 \Rightarrow \delta = 3\].
This tells us the exponent \delta that characterizes the critical isotherm, revealing how the system's magnetization responds to the applied magnetic field precisely at \texttt{T_c}.
This is crucial in understanding the abrupt change in magnetization at the phase transition.
Magnetic Susceptibility
Magnetic susceptibility (\texttt{\chi}) is a measure of how much the magnetization \texttt{M} changes when an external magnetic field \texttt{B} is applied.
Near the critical point, \texttt{\chi} diverges following a power law characterized by the critical exponent \texttt{\gamma}, calculated as \texttt{\epsilon^{−\gamma}}.
From the scaling relation, equating magnetic terms gave \[\lambda^{\gamma} = \lambda^5 - \lambda^2 = \lambda^3\], which simplifies to \texttt{\gamma = 3/2}.
This critical exponent informs us about the extent of susceptibility divergence, helping us understand how the system becomes extremely responsive to external fields near the transition.
Heat Capacity
Heat capacity (\texttt{C}) measures the amount of heat needed to change the system's temperature.
At the critical point, it diverges following a power law determined by the critical exponent \texttt{\alpha}, represented as \texttt{\epsilon^{-\alpha}}.
Using the scaling relation, we found \[\lambda^{\alpha} = \lambda^5\], leading us to derive \texttt{\alpha = 5/2}.
This tells us how heat capacity behaves near the critical temperature, showing a significant increase in energy required to change the system's temperature.

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