The density of states of an ideal Bose-Einstein gas in a cubic box of volume \(V\) is $$ g(E)= \begin{cases}\alpha E^{3} & \text { if } \quad E>0 \\ 0 & \text { if } \quad E<0\end{cases} $$ where \(\alpha\) is a constant. Compute the critical temperature for Bose- Einstein condensation.

Short Answer

Expert verified
The critical temperature for Bose-Einstein condensation is \( T_c = \left(\frac{15 N}{\alpha k_B^4 \pi^4}\right)^{1/4} \).

Step by step solution

01

Understand the Density of States Function

The density of states function for an ideal Bose-Einstein gas in a cubic box of volume V is given as follows:\[ g(E) = \begin{cases} \alpha E^3 & \text{if} \quad E>0 \ 0 & \text{if} \quad E<0 \end{cases} \]Here, \(\alpha\) is a constant and we need to find the critical temperature for Bose-Einstein condensation.
02

Apply the Condition for Bose-Einstein Condensation

The Bose-Einstein condensation occurs when the ground state becomes macroscopically occupied. The critical temperature \(T_c\) can be found using the condition:\[ N = \int_0^{\infty} \frac{g(E)}{e^{E / (k_B T_c)} - 1} \, dE \]where \(N\) is the number of particles, \(E\) is the energy, \(k_B\) is the Boltzmann constant, and \(T_c\) is the critical temperature.
03

Substitute the Density of States Function

Substitute the given density of states function \(g(E)\) into the integral:\[ N = \int_0^{\infty} \frac{\alpha E^3}{e^{E / (k_B T_c)} - 1} \, dE \]
04

Simplify the Integral

Introduce a dimensionless variable \(x\) such that \(x = E / (k_B T_c) \). This transforms the integral:\[ N = \alpha (k_B T_c)^4 \int_0^{\infty} \frac{x^3}{e^x - 1} \, dx \]The integral \(\int_0^{\infty} \frac{x^3}{e^x - 1} \, dx \) is a known value and equals \(\frac{\pi^4}{15} \).
05

Solve for the Critical Temperature \(T_c\)

Now, solve for \(T_c\):\[ N = \alpha (k_B T_c)^4 \frac{\pi^4}{15} \]Rearrange to find \(T_c\):\[ T_c = \left(\frac{15 N}{\alpha k_B^4 \pi^4}\right)^{1/4} \]

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Density of States
The concept of the 'density of states' (DOS) is crucial in understanding how particles are distributed among available energy levels. In the context of an ideal Bose-Einstein gas, the DOS function defines how many states are available at a certain energy level. Here, the DOS is given by: \[ g(E) = \begin{cases} \alpha E^3 & \text{if} \quad E>0 \ 0 & \text{if} \quad E<0 \end{cases} \]For positive energies, it follows a cubic relationship (E^3), which means the number of states increases rapidly with energy. The constant \text\beta is unique to the system's properties, like volume and particle mass. Understanding these states' distribution helps predict the critical temperature (T_c) for Bose-Einstein condensation when particles congregate in the lowest energy state.
Critical Temperature
The critical temperature, T_c, marks the point where Bose-Einstein condensation occurs, causing a large fraction of particles to settle into the ground state.To find T_c, we use the condition: \[ N = \int_0^{\infty} \frac{g(E)}{e^{E / (k_B T_c)} - 1} \, dE \]Here:
  • N represents the number of particles
  • E is the energy
  • k_B is the Boltzmann constant
  • \text Tc is the critical temperature.
By substituting the given DOS function and simplifying through integral transformation, we get: \[ T_c = \left(\frac{15 N}{text'alpha k_B^4 \pi^4}\right)^{1/4} \]This formula helps us calculate the exact temperature where condensation begins for a system of bosons (particles following Bose-Einstein statistics).
Integral Transformation
In solving for the critical temperature, an integral transformation is essential. The transformation process simplifies complex integrals by changing variables. Initially, we have:\[ N = \int_0^{\infty} \frac{text'alpha E^3}{e^{E / (k_B T_c)} - 1} \, dE \]Introducing a dimensionless variable x, where \[ x = E / (k_B T_c) \], changes the integral as follows:\[ N = \text'alpha (k_B T_c)^4 \int_0^{\infty} \frac{x^3}{e^x - 1} \, dx \]The integral \[ \int_0^{\infty} \frac{x^3}{e^x - 1} \, dx \] is known and equal to \frac{\pi^4}{15}. Simplifying and solving helps us derive the expression for T_c. This approach is vital in physical problems to make equations more manageable and solvable by applying known mathematical results.

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Most popular questions from this chapter

Electrons in a piece of copper metal can be assumed to behave like an ideal Fermi gas. Copper metal in the solid state has a mass density of \(9 \mathrm{~g} / \mathrm{cm}^{3}\). Assume that each copper atom donates one electron to the Fermi gas. Assume the system is at \(T=0 \mathrm{~K}\). (a) Compute the Fermi energy, \(\varepsilon_{\mathrm{F}}\), of the electron gas. (b) Compute the Fermi "temperature", \(T_{\mathrm{F}}=\varepsilon_{\mathrm{P}} / \mathrm{k}_{\mathrm{B}}\).

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