Carefully plot the Maxwell speed distribution for nitrogen molecules at T=300K and atT=600K. Plot both graphs on the same axes, and label the axes with numbers.

Short Answer

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The maxwell speed distribution graph for nitrogen molecules at T=300Kand T=600Kis

Step by step solution

01

Given information 

We are given that,

The maxwell speed distribution can then be written

D(v)=4πv2vo2t-32e-v2v02t

T=300k,600k

02

Simplify

Let us define the constant v02kT/mfor T=300k. The mass of a nitrogen molecule is28u,

So, vo=2k(300k)m=2(1.38×10-23J/k)(300k)28(1.66×10-27kg)=422m/s

The maxwell speed distribution can then be written

D(v)=4πv2vo2t-32e-v2v02t,

Where t is the temperature in units of 300k. To plot this function fort=1and t=2,

I gave Mathematicalthe following instruction:

v0=422;maxwell[t,v]:=2.257×(v2/v30)×t-(-1.5)×Exp[-v2/(v02×t)]Plot[{maxwell[1,v],maxwell[2,v]},{v,0,1700}

Here the plot graph


Notice that the area under each curve is equal to 1. Therefore, as the location of the peak

Moves to the right (in proportion to T), its height must decrease.

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Most popular questions from this chapter

The most common measure of the fluctuations of a set of numbers away from the average is the standard deviation, defined as follows.

(a) For each atom in the five-atom toy model of Figure 6.5, compute the deviation of the energy from the average energy, that is, Ei-E¯,fori=1to5. Call these deviations ΔEi.

(b) Compute the average of the squares of the five deviations, that is, ΔEi2¯. Then compute the square root of this quantity, which is the root-mean- square (rms) deviation, or standard deviation. Call this number σE. Does σEgive a reasonable measure of how far the individual values tend to stray from the average?

(c) Prove in general that

σE2=E2¯-(E¯)2

that is, the standard deviation squared is the average of the squares minus the square of the average. This formula usually gives the easier way of computing a standard deviation.

(d) Check the preceding formula for the five-atom toy model of Figure 6.5.

In the numerical example in the text, I calculated only the ratio of the probabilities of a hydrogen atom being in two different states. At such a low temperature the absolute probability of being in a first excited state is essentially the same as the relative probability compared to the ground state. Proving this rigorously, however, is a bit problematic, because a hydrogen atom has infinitely many states.

(a) Estimate the partition function for a hydrogen atom at 5800 K, by adding the Boltzmann factors for all the states shown explicitly in Figure 6.2. (For simplicity you may wish to take the ground state energy to be zero, and shift the other energies according!y.)

(b) Show that if all bound states are included in the sum, then the partition function of a hydrogen atom is infinite, at any nonzero temperature. (See Appendix A for the full energy level structure of a hydrogen atom.)

(c) When a hydrogen atom is in energy level n, the approximate radius of the electron wavefunction is a0n2, where ao is the Bohr radius, about 5 x 10-11 m. Going back to equation 6.3, argue that the PdV term is Tot negligible for the very high-n states, and therefore that the result of part (a), not that of part (b), gives the physically relevant partition function for this problem. Discuss.

A lithium nucleus has four independent spin orientations, conventionally labeled by the quantum number m = -3/2, -1/2, 1/2, 3/2. In a magnetic field B, the energies of these four states are E = mμB, where μ the constant is 1.03 x 10-7 eV/T. In the Purcell-Pound experiment described in Section 3.3, the maximum magnetic field strength was 0.63 T and the temperature was 300 K. Calculate the probability of a lithium nucleus being in each of its four spin states under these conditions. Then show that, if the field is suddenly reversed, the probabilities of the four states obey the Boltzmann distribution for T =-300 K.

In the real world, most oscillators are not perfectly harmonic. For a quantum oscillator, this means that the spacing between energy levels is not exactly uniform. The vibrational levels of an H2 molecule, for example, are more accurately described by the approximate formula

Enϵ1.03n-0.03n2,n=0,1,2,

where ϵ is the spacing between the two lowest levels. Thus, the levels get closer together with increasing energy. (This formula is reasonably accurate only up to about n = 15; for slightly higher n it would say that En decreases with increasing n. In fact, the molecule dissociates and there are no more discrete levels beyond n 15.) Use a computer to calculate the partition function, average energy, and heat capacity of a system with this set of energy levels. Include all levels through n = 15, but check to see how the results change when you include fewer levels Plot the heat capacity as a function of kT/ϵ. Compare to the case of a perfectly harmonic oscillator with evenly spaced levels, and also to the vibrational portion of the graph in Figure 1.13.

Although an ordinary H2 molecule consists of two identical atoms, this is not the case for the molecule HD, with one atom of deuterium (i.e., heavy hydrogen, 2H). Because of its small moment of inertia, the HD molecule has a relatively large value of ϵ:0.0057eV At approximately what temperature would you expect the rotational heat capacity of a gas of HD molecules to "freeze out," that is, to fall significantly below the constant value predicted by the equipartition theorem?

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