Carefully plot the Maxwell speed distribution for nitrogen molecules at T=300K and atT=600K. Plot both graphs on the same axes, and label the axes with numbers.

Short Answer

Expert verified

The maxwell speed distribution graph for nitrogen molecules at T=300Kand T=600Kis

Step by step solution

01

Given information 

We are given that,

The maxwell speed distribution can then be written

D(v)=4πv2vo2t-32e-v2v02t

T=300k,600k

02

Simplify

Let us define the constant v02kT/mfor T=300k. The mass of a nitrogen molecule is28u,

So, vo=2k(300k)m=2(1.38×10-23J/k)(300k)28(1.66×10-27kg)=422m/s

The maxwell speed distribution can then be written

D(v)=4πv2vo2t-32e-v2v02t,

Where t is the temperature in units of 300k. To plot this function fort=1and t=2,

I gave Mathematicalthe following instruction:

v0=422;maxwell[t,v]:=2.257×(v2/v30)×t-(-1.5)×Exp[-v2/(v02×t)]Plot[{maxwell[1,v],maxwell[2,v]},{v,0,1700}

Here the plot graph


Notice that the area under each curve is equal to 1. Therefore, as the location of the peak

Moves to the right (in proportion to T), its height must decrease.

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with Vaia!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

Use a computer to sum the rotational partition function (equation 6.30) algebraically, keeping terms through j = 6. Then calculate the average energy and the heat capacity. Plot the heat capacity for values ofkT/ϵ ranging from 0 to 3. Have you kept enough terms in Z to give accurate results within this temperature range?

Prove that, for any system in equilibrium with a reservoir at temperature T, the average value of E2 is

E2¯=1Z2Zβ2

Then use this result and the results of the previous two problems to derive a formula for σEin terms of the heat capacity, C=E¯/T

You should findσE=kTC/k

Each of the hydrogen atom states shown in Figure 6.2 is actually twofold degenerate, because the electron can be in two independent spin states, both with essentially the same energy. Repeat the calculation given in the text for the relative probability of being in a first excited state, taking spin degeneracy into account. Show that the results are unaffected.

Estimate the probability that a hydrogen atom at room temperature is in one of its first excited states (relative to the probability of being in the ground state). Don't forget to take degeneracy into account. Then repeat the calculation for a hydrogen atom in the atmosphere of the starγ UMa, whose surface temperature is approximately 9500 K.

Prove that, for any system in equilibrium with a reservoir at temperature T, the average value of the energy is

E¯=-1ZZβ=-βlnZ

where β=1/kT. These formulas can be extremely useful when you have an explicit formula for the partition function.

See all solutions

Recommended explanations on Physics Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.

Sign-up for free