Use the Maxwell distribution to calculate the average value of v2for the molecules of an ideal gas. Check that your answer agrees with equation 6.41.

Short Answer

Expert verified

The required average value is 3kTmand it matches with the given equation.

Step by step solution

01

Step1. Given information

The Maxwell speed distribution function is give by

Dv=m2πkT324πv2e-mv22kT................................(1)

02

Step 2. Calculation

The formula to calculate the average of v2is given by

v2=0v2Dvdv....................(2)

Substitute the distribution function from equation (1) into equation (2) to calculate the required average value.

v2=0v2m2πkT324πv2e-mv22kTdv=4πm2πkT320v4e-mv22kTdv................(3)

Substitute xfor m2kTvinto equation (3) and evaluate the required value.

role="math" localid="1647007293675" v2=4πm2πkT322kTm520x4e-x2dx=4πm2πkT322kTm523π8=3kTm

The rms speed is defined as

vrms=v2...................(4)

Substitute 3kTmfor v2into equation (4) to obtain the rms speed.

vrms=3kTm

Thus, the above equation exactly matches with equation 6.41.

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Most popular questions from this chapter

In the real world, most oscillators are not perfectly harmonic. For a quantum oscillator, this means that the spacing between energy levels is not exactly uniform. The vibrational levels of an H2 molecule, for example, are more accurately described by the approximate formula

Enϵ1.03n-0.03n2,n=0,1,2,

where ϵ is the spacing between the two lowest levels. Thus, the levels get closer together with increasing energy. (This formula is reasonably accurate only up to about n = 15; for slightly higher n it would say that En decreases with increasing n. In fact, the molecule dissociates and there are no more discrete levels beyond n 15.) Use a computer to calculate the partition function, average energy, and heat capacity of a system with this set of energy levels. Include all levels through n = 15, but check to see how the results change when you include fewer levels Plot the heat capacity as a function of kT/ϵ. Compare to the case of a perfectly harmonic oscillator with evenly spaced levels, and also to the vibrational portion of the graph in Figure 1.13.

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