Use the Maxwell distribution to calculate the average value of v2for the molecules of an ideal gas. Check that your answer agrees with equation 6.41.

Short Answer

Expert verified

The required average value is 3kTmand it matches with the given equation.

Step by step solution

01

Step1. Given information

The Maxwell speed distribution function is give by

Dv=m2πkT324πv2e-mv22kT................................(1)

02

Step 2. Calculation

The formula to calculate the average of v2is given by

v2=0v2Dvdv....................(2)

Substitute the distribution function from equation (1) into equation (2) to calculate the required average value.

v2=0v2m2πkT324πv2e-mv22kTdv=4πm2πkT320v4e-mv22kTdv................(3)

Substitute xfor m2kTvinto equation (3) and evaluate the required value.

role="math" localid="1647007293675" v2=4πm2πkT322kTm520x4e-x2dx=4πm2πkT322kTm523π8=3kTm

The rms speed is defined as

vrms=v2...................(4)

Substitute 3kTmfor v2into equation (4) to obtain the rms speed.

vrms=3kTm

Thus, the above equation exactly matches with equation 6.41.

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Most popular questions from this chapter

You might wonder why all the molecules in a gas in thermal equilibrium don't have exactly the same speed. After all, when two molecules collide, doesn't the faster one always lose energy and the slower one gain energy? And if so, wouldn't repeated collisions eventually bring all the molecules to some common speed? Describe an example of a billiard-ball collision in which this is not the case: The faster ball gains energy and the slower ball loses energy. Include numbers, and be sure that your collision conserves both energy and momentum.

Fill in the steps between equations 6.51 and 6.52, to determine the average speed of the molecules in an ideal gas.

Each of the hydrogen atom states shown in Figure 6.2 is actually twofold degenerate, because the electron can be in two independent spin states, both with essentially the same energy. Repeat the calculation given in the text for the relative probability of being in a first excited state, taking spin degeneracy into account. Show that the results are unaffected.

In the real world, most oscillators are not perfectly harmonic. For a quantum oscillator, this means that the spacing between energy levels is not exactly uniform. The vibrational levels of an H2 molecule, for example, are more accurately described by the approximate formula

Enϵ1.03n-0.03n2,n=0,1,2,

where ϵ is the spacing between the two lowest levels. Thus, the levels get closer together with increasing energy. (This formula is reasonably accurate only up to about n = 15; for slightly higher n it would say that En decreases with increasing n. In fact, the molecule dissociates and there are no more discrete levels beyond n 15.) Use a computer to calculate the partition function, average energy, and heat capacity of a system with this set of energy levels. Include all levels through n = 15, but check to see how the results change when you include fewer levels Plot the heat capacity as a function of kT/ϵ. Compare to the case of a perfectly harmonic oscillator with evenly spaced levels, and also to the vibrational portion of the graph in Figure 1.13.

Some advances textbooks define entropy by the formula

S=-ksPslnPs

where the sum runs over all microstates accessible to the system and Psis the probability of the system being in microstate s.

(a) For an isolated system, role="math" localid="1647056883940" Ps=1Ωfor all accessible states s. Show that in this case the preceding formula reduces to our familiar definition of entropy.

(b) For a system in thermal equilibrium with a reservoir at temperatureT,role="math" localid="1647057328146" Ps=e-EskTZ. Show that in this case as well, the preceding formula agrees with what we already know about entropy.

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