Imagine a world in which space is two-dimensional, but the laws of physics are otherwise the same. Derive the speed distribution formula for an ideal gas of nonrelativistic particles in this fictitious world, and sketch this distribution. Carefully explain the similarities and differences between the two-dimensional and three-dimensional cases. What is the most likely velocity vector? What is the most likely speed?

Short Answer

Expert verified

The probability of is, Pv=m2πkT2πve-mv22kT

The most likely velocity and speed is, vmax=kTm

Step by step solution

01

Given information 

We need to find out the probability and most likely velocity for a world in which space is two-dimensional, but the laws of physics are otherwise the same.

02

Explanation

The probability of a molecule in 2D plane is proportional to Boltzmann factor e-mv22kT, in 2D plane the velocity life is inside the circle of radius v, which means that the no. of the velocity vectors is proportional to the circumference of this circle, i.e. 2πv, so we can give the probability as

role="math" localid="1650192711584" P(v)2πve-mv22kT

P(v)=C×2πve-mv22kT Let it be equation 1

Where C is constant

To find this constant we use the fact that the integration of the probability all over space is unity,

So,

0P(v)-C×2π0ve-mv22kT-1

But,

xe-ax2=-e-ax22a

Here, we have a=m2kT

So,

C×2πkTme-mv22kT0=1C×2πkTm0-1=1C×2πkTm=1C=m2πkT

Now, substitute above value of C in (1) to get,

Pv=m2πkT2πve-mv22kT

03

Clarification   

As in 3D plane the probability fall exponentially e-v2as v.However, at low velocities the linear term dominate, so instead of the parabolic we have linear, plot the probability we set:

v'=vmkT

In terms of v'the probability can be given as,

Pv=mkTv'e-v'22

So, we plot a graph between P(v)and v', were the slope of the linear part of the graph is,

Slope= mkT

04

Simplify

To find the most likely speed, we take the derivative of the probability then set it equals to zero,

dPdv=0ddvve-av2=0

Here, a=m2kT

So,

-2av2e-av2+e-av2=02av2=1v=12av=kTm

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Most popular questions from this chapter

At room temperature, what fraction of the nitrogen molecules in the air are moving at less than300m/s?

You might wonder why all the molecules in a gas in thermal equilibrium don't have exactly the same speed. After all, when two molecules collide, doesn't the faster one always lose energy and the slower one gain energy? And if so, wouldn't repeated collisions eventually bring all the molecules to some common speed? Describe an example of a billiard-ball collision in which this is not the case: The faster ball gains energy and the slower ball loses energy. Include numbers, and be sure that your collision conserves both energy and momentum.

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{a) Show that the average position of the particle is given by

x=xe-βuxdxe-βuxdx

where each integral is over the entire xaxis.

A one-dimensional potential well. The higher the temperature, the farther the particle will stray from the equilibrium point.

(b) If the temperature is reasonably low (but still high enough for classical mechanics to apply), the particle will spend most of its time near the bottom of the potential well. In that case we can expand u(z) in a Taylor series about the equilibrium point

ux=ux0+x-x0dudxx0+12x-x02d2udx2x0+13!x-x03d3udx3x0+........

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(c) If we keep the cubic term in the Taylor series as well, the integrals in the formula for xbecome difficult. To simplify them, assume that the cubic term is small, so its exponential can be expanded in a Taylor series (leaving the quadratic term in the exponent). Keeping only the smallest temperature-dependent term, show that in this limit x differs from by a term proportional to kT. Express the coefficient of this term in terms of the coefficients of the Taylor series ux

(d) The interaction of noble gas atoms can be modeled using the Lennard Jones potential,

ux=u0x0x12-2x0x6

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