Home owners and builders discuss thermal conductivities in terms of the value (Rfor resistance) of a material, defined as the thickness divided by the thermal conductivity:

RΔxkt

(a) Calculate the Rvalue of a 1/8-inch(3.2mm) piece of plate glass, and then of a 1mmlayer of still air. Express both answers in SI units.

(b) In the United States, Rvalues of building materials are normally given in English units,Fft2hr/Btu. A Btu, or British thermal unit, is the energy needed to raise the temperature of a pound of water 1F. Work out the conversion factor between the SI and English units for values. Convert your answers from part (a) to English units.

(c) Prove that for a compound layer of two different materials sandwiched together (such as air and glass, or brick and wood), the effective total Rvalue is the sum of the individual Rvalues.

(d) Calculate the effective Rvalue of a single piece of plate glass with a 1.0mmlayer of still air on each side. (The effective thickness of the air layer will depend on how much wind is blowing; 1mmis of the right order of magnitude under most conditions.) Using this effective Rvalue, make a revised estimate of the heat loss through a 1m2single-pane window when the temperature in the room is 20Chigher than the outdoor temperature.

Short Answer

Expert verified

From the following

a. The value of Rboth glass and air has been found.

Rair=0.0385J1sm2K

Rglass=0.004J1sm2K

b. By conversion of units

1Fft2hrBtu1=0.176Km2sJ

Rair=0.2187Fft2hrBtu1

Rglass=0.0227Fft2hrBtu1

c. The effective value of R

Rc=R1+R2

d. Therefore using the effectiveRvalue we get,

Rc=0.081J1sm2K

QΔt=246.91watts

Step by step solution

01

Thermal conductivity (part a)

In the construction industry, thermal conductivity is frequently expressed in terms of the Rvalue, which is defined as:

R=Δxkt

Since Rdepends on the inverse of the thermal conductivity and directly on the thickness of the insulating material, a larger Rmeans a better insulator.

For the 1mmlayer of still air with kt=0.026Js1m1K1, we have:

Rair=Δxkt=0.0010.026=0.0385J1sm2K

Given that kt=0.8Js1m1K1for glass, the Rvalue of a 3.2mmthick sheet of glass is:

Rglass=Δxkt=0.00320.8=0.004J1sm2K

Thus if there is a 1mmlayer of still air next to a window, it actually provides more insulation than the window glass itself.

02

Conversion of Units (part b)

In the US, the units of Rare Fft2hrBtu1where a British thermal unit Btuis the amount of energy necessary to elevate one pound of water by 1F. To convert to SI units of R, we need to convert 1Btuto Joules. One Fahrenheit degree is59of a Kelvin, there are 453.592grams per pound, and 4.186joules are required to raise 1a gram of water by 1K. Therefore:

1Btu=59K×(4.186)J×(453.592)g=1054.85J

One foot is 0.3048mand 1hour is 3600seconds, so

1F×ft2×hr×Btu1=59K(0.3048)2m2×(3600)s×(1054.85)1J1

1Fft2hrBtu1=0.176Km2sJ

The previous Rvalues in English units are therefore:

Rair=10.176×0.0385=0.2187Fft2hrBtu1

Rglass=10.176×0.004=0.0227Fft2hrBtu1

03

Pictorial Representation

The Rvalues of a compound layer of two different materials are the sum of the individual Rvalues. This can be seen as follows. Assume we have a composite layer made up of two components.: material 1and material 2. The temperature on the exposed side of the material 2is T2and on the material 1side is T1. At the place where the two materials meet, the temperature isTa.


04

At a steady flow rate of flow of heat 

The rate of heat flow across the two layers must be the same in the steady-state (otherwise, heat would build up elsewhere), and employing QΔt=kt1AΔTΔx1, so from the material 1we have:

Let be Equation (1)

QΔt=kt1AΔTΔx1=kt1ATaT1Δx1

and for material 2, we have equation (2):

QΔt=kt2AΔTΔx2=kt2AT2TaΔx2

by equating equation (1) and equation (2), we have equation (3):

kt2T2TaΔx2=kt1TaT1Δx1

where A(area) is dropping out since in both layers the area is the same. we have equation (4):

R1=Δx1kt1R2=Δx2kt2

substitute from (4) into (3), we get equation (5),

T2TaR2=TaT1R1

The overall rate of heat transfer across the compound layer must now be the same as well.. If we define Rcit to be the effective Rvalue of the compound layer, then:

T2TaR2=TaT1R1=T2T1Rc

so we have two equations, let's be equation (6).

T2TaR2=TaT1R1TaT1R1=T2T1Rc

05

Solving Ta to find Rc

now we need to solve these two equations for Rc. From the first equation, we can solve for Ta:

T2TaR2=TaT1R1R1T2R1Ta=R2TaR2T1

R1T2+R2T1=R2Ta+R1TaR1T2+R2T1=TaR2+R1

Ta=R1T2+R2T1R2+R1

Substituting into the second equation in (6) we can solve for Rc:

TaT1R1=T2T1Rc1R1TaT1R1=T2T1Rc

1R1R1T2+R2T1R2+R1T1R1=T2T1Rc

R1T2+R2T1R1R2+R1R2+R1T1R2+R1R1=T2T1Rc

R1T2+R2T1R2T1R1T1R1R2+R1=T2T1Rc

R1T2T1R1R2+R1=T2T1Rc

Rc=R1+R2

06

To find the effective R value

Using this compound Rvalue, we can estimate the rate of heat loss from a 1m2single-pane window of thickness 3.2mm, but with a 1mmlayer of still air on each side. The effective Rvalue of this system is:

localid="1650266582013" Rc=Rglass+2×Rair

using the results from step 1,

localid="1650266585531" Rair=0.0385J1sm2K

localid="1650266588974" Rglass=0.004J1sm2K

so, the effective localid="1650266593411" Rvalue of this system is, therefore:

localid="1650266597424" Rc=0.004+2×0.0385=0.081J1sm2K

When the temperature difference is localid="1650266601163" ΔT=20K, the rate of heat is:

QΔt=ktAΔTΔx

with, localid="1650266605707" Rc=Δxktso:

localid="1650266613094" QΔt=AΔTRc

substitute,

localid="1650266651710" QΔt=1×200.081=246.91localid="1650266657465" watts

This compares with the heat loss through the glass on its own localid="1650266667372" AΔTRglass=5000localid="1650266673006" watts. Thus the air layer provides most of the insulation.

Therefore, it is concluded that,

localid="1650266679151" Rair=0.0385J1sm2K

localid="1650266683604" Rglass=0.004J1sm2K

localid="1650266688380" 1Fft2hrBtu1=0.176Km2sJ,

localid="1650266693304" Rair=0.2187Fft2hrBtu1

localid="1650266702329" Rglass=0.0227Fft2hrBtu1

localid="1650266707608" Rc=R1+R2

localid="1650266713776" Rc=0.081J1sm2K,QΔt=246.91watts

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Most popular questions from this chapter

Calculate the total thermal energy in a gram of lead at room temperature, assuming that none of the degrees of freedom are "frozen out" (this happens to be a good assumption in this case).

In analogy with the thermal conductivity, derive an approximate formula for the viscosity of an ideal gas in terms of its density, mean free path, and average thermal speed. Show explicitly that the viscosity is independent of pressure and proportional to the square root of the temperature. Evaluate your formula numerically for air at room temperature and compare to the experimental value quoted in the text.

Problem 1.36. In the course of pumping up a bicycle tire, a liter of air at atmospheric pressure is compressed adiabatically to a pressure of 7 atm. (Air is mostly diatomic nitrogen and oxygen.)

(a) What is the final volume of this air after compression?

(b) How much work is done in compressing the air?

(c) If the temperature of the air is initially300K , what is the temperature after compression?

Make a rough estimate of the thermal conductivity of helium at room temperature. Discuss your result, explaining why it differs from the value for air.

Even at low density, real gases don’t quite obey the ideal gas law. A systematic way to account for deviations from ideal behavior is the virial

expansion,

PVnRT(1+B(T)(V/n)+C(T)(V/n)2+)

where the functions B(T), C(T), and so on are called the virial coefficients. When the density of the gas is fairly low, so that the volume per mole is large, each term in the series is much smaller than the one before. In many situations, it’s sufficient to omit the third term and concentrate on the second, whose coefficient B(T)is called the second virial coefficient (the first coefficient is 1). Here are some measured values of the second virial coefficient for nitrogen (N2):

T(K)
B(cm3/mol)
100–160
200–35
300–4.2
4009.0
50016.9
60021.3
  1. For each temperature in the table, compute the second term in the virial equation, B(T)/(V/n), for nitrogen at atmospheric pressure. Discuss the validity of the ideal gas law under these conditions.
  2. Think about the forces between molecules, and explain why we might expect B(T)to be negative at low temperatures but positive at high temperatures.
  3. Any proposed relation between P, V, andT, like the ideal gas law or the virial equation, is called an equation of state. Another famous equation of state, which is qualitatively accurate even for dense fluids, is the van der Waals equation,
    (P+an2V2)(Vnb)=nRT
    where a and b are constants that depend on the type of gas. Calculate the second and third virial coefficients (Band C) for a gas obeying the van der Waals equation, in terms of aand b. (Hint: The binomial expansion says that (1+x)p1+px+12p(p1)x2, provided that |px|1. Apply this approximation to the quantity [1(nb/V)]1.)
  4. Plot a graph of the van der Waals prediction for B(T), choosing aand bso as to approximately match the data given above for nitrogen. Discuss the accuracy of the van der Waals equation over this range of conditions. (The van der Waals equation is discussed much further in Section 5.3.)
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