In analogy with the thermal conductivity, derive an approximate formula for the viscosity of an ideal gas in terms of its density, mean free path, and average thermal speed. Show explicitly that the viscosity is independent of pressure and proportional to the square root of the temperature. Evaluate your formula numerically for air at room temperature and compare to the experimental value quoted in the text.

Short Answer

Expert verified

The experimental value quoted within the text is

η=12ρv¯,

η=3mKT8πr2,

ηair=3.88×105Nm2s

Step by step solution

01

Path and Velocity

The atomic length is r, while the energy of 1monomer is m. Suppose a skinny rectangular sheet of gas in between plates; electrons within a distance of such slab's midline can across it whether or not they are travelling within the same direction. The common half the molecules in each half are travelling towards the midpoint so if the average horizontal momentum of the molecules on side iis pifor i=1,2,, then in a very time Δt(that is, the time it takes a median molecule to travel the momentum transferred is:

14πr2VN

v¯3KTm

Δp=12p1p2

but the momentum is that the mass multiplied by velocity,

p1=Mux,1,p2=Mux,2

Δp=M2ux,1ux,2

p1=Mux,1,p2=Mux,2

02

Mean Path

The slabs' total force acting is:

FxA=ΔpAΔt

Once we transfer F=ΔpΔtfrom formula Δpwith , then need:

FxA=1AΔt[Δp]=1AΔtM2duxdz

has been wont to scale, hence

FxA=M22AΔtduxdz

Instead, the intensity ρis capable the load Mout over freed mean path scaled by the per sectional space, and Δt is that the time required the particle to maneuver one freedom meant line l, like in:

MA=ρΔt=v¯

As a answer, equation are as chooses to follow:

FxA=12MAΔtduxdz=12ρv¯duxdz

FxA=12ρv¯duxdz

FxA=ηduxdz

η=12ρv¯

03

Density

Average volume from its respective components. Its density of just an noble gas is obtained by multiplying the typical of an air molecule mbut by full different molecules Nout over given quantity V, or:

ρ=mNV

η=12mNVv¯

η=12mNV[][v¯]=12mNV14πr2VN3KTm

η=3mKT8πr2

04

Average Mass

The dense of noble gas is up to average mass of surrounding air m weighted by the tons. The dense of just an inert fluid is capable average mass of all its molecules. The concentration of wind is calculated based:

ρ=mNV

ρ=4.81×1026×6.022×10230.028=1.0345kgm3

ρ=1.0345kgm3

Unless we've single mole of air under atmosphere pressure, the capacity of 1 mole the least bit is m=4.81×1026kg, in addition because the molarity in one mole is indeed the Avogadro number , 1.9×105Nm2then thethe degreeis:

η=12ρv¯=12×1.0345×500×1.5×107

=3.88×105N2m2s

ηoir=3.88×105Nm2s

Are using data from Schroeder's book about ambient air.

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Most popular questions from this chapter

By applying Newton’s laws to the oscillations of a continuous medium, one can show that the speed of a sound wave is given by

cs=Bρ,

where ρis the density of the medium (mass per unit volume) and B is the bulk modulus, a measure of the medium’s stiffness? More precisely, if we imagine applying an increase in pressure ΔPto a chunk of the material, and this increase results in a (negative) change in volume ΔV, then B is defined as the change in pressure divided by the magnitude of the fractional change in volume:

B=ΔPΔV/V

This definition is still ambiguous, however, because I haven't said whether the compression is to take place isothermally or adiabatically (or in some other way).

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