Chapter 1: Q. 1.67 (page 48)
Make a rough estimate of how far food coloring (or sugar) will diffuse through water in one minute.
Short Answer
In one minute, the food coloring (or sugar) will diffuse through the water.
Chapter 1: Q. 1.67 (page 48)
Make a rough estimate of how far food coloring (or sugar) will diffuse through water in one minute.
In one minute, the food coloring (or sugar) will diffuse through the water.
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Derive the equation 1.40 from the equation 1.39
Consider the combustion of one mole of methane gas:
The system is at standard temperature and pressure both before and after the reaction.
(a) First imagine the process of converting a mole of methane into its elemental constituents (graphite and hydrogen gas). Use the data at the back of this book to find for this process.
(b) Now imagine forming a mole of and two moles of water vapor from their elemental constituents. Determine for this process.
(c) What is for the actual reaction in which methane and oxygen form carbon dioxide and water vapor directly? Explain.
(d) How much heat is given off during this reaction, assuming that no "other" forms of work are done?
(e) What is the change in the system's energy during this reaction? How would your answer differ if theended up as liquid water instead of vapor?
(f) The sun has a mass ofand gives off energy at a rate of watts. If the source of the sun's energy were ordinary combustion of a chemical fuel such as methane, about how long could it last?
Put a few spoonfuls of water into a bottle with a tight lid. Make sure everything is at room temperature, measuring the temperature of the water with a thermometer to make sure. Now close the bottle and shake it as hard as you can for several minutes. When you're exhausted and ready to drop, shake it for several minutes more. Then measure the temperature again. Make a rough calculation of the expected temperature change, and compare.
An ideal diatomic gas, in a cylinder with a movable piston, undergoes the rectangular cyclic process shown in the given figure.
Assume that the temperature is always such that rotational degrees of freedom are active, but vibrational modes are "frozen out." Also assume that the only type of work done on the gas is quasistatic compression-expansion work.
(a) For each of the four steps A through D, compute the work done on the gas, the heat added to the gas, and the change in the energy content of the gas. Express all answers in terms of . (Hint: Compute before Q, using the ideal gas law and the equipartition theorem.)
(b) Describe in words what is physically being done during each of the four steps; for example, during step A, heat is added to the gas (from an external flame or something) while the piston is held fixed.
(c) Compute the net work done on the gas, the net heat added to the gas, and the net change in the energy of the gas during the entire cycle. Are the results as you expected? Explain briefly.
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