Chapter 1: Q. 1.67 (page 48)
Make a rough estimate of how far food coloring (or sugar) will diffuse through water in one minute.
Short Answer
In one minute, the food coloring (or sugar) will diffuse through the water.
Chapter 1: Q. 1.67 (page 48)
Make a rough estimate of how far food coloring (or sugar) will diffuse through water in one minute.
In one minute, the food coloring (or sugar) will diffuse through the water.
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Get started for freeIn Problem 1.16 you calculated the pressure of earth's atmosphere as a function of altitude, assuming constant temperature. Ordinarily, however, the temperature of the bottom most 10-15 km of the atmosphere (called the troposphere) decreases with increasing altitude, due to heating from the ground (which is warmed by sunlight). If the temperature gradient |dT/dz| exceeds a certain critical value, convection will occur: Warm, low-density air will rise, while cool, high-density air sinks. The decrease of pressure with altitude causes a rising air mass to expand adiabatically and thus to cool. The condition for convection to occur is that the rising air mass must remain warmer than the surrounding air despite this adiabatic cooling.
(a) Show that when an ideal gas expands adiabatically, the temperature and pressure are related by the differential equation
(b) Assume that dT/dz is just at the critical value for convection to begin, so that the vertical forces on a convecting air mass are always approximately in balance. Use the result of Problem 1.16b to find a formula for dT/dz in this case. The result should be a constant, independent of temperature and pressure, which evaluates to approximately -10oC/ km. This fundamental meteorological quantity is known as the dry adiabatic lapse rate.
Heat capacities are normally positive, but there is an important class of exceptions: systems of particles held together by gravity, such as stars and star clusters.
Consider a system of just two particles, with identical masses, orbiting in circles about their center of mass. Show that the gravitational potential energy of this system is-times the total kinetic energy.
The conclusion of part turns out to be true, at least on average, for any system of particles held together by mutual gravitational attraction:
Here each refers to the total energy (of that type) for the entire system, averaged over some sufficiently long time period. This result is known as the virial theorem. (For a proof, see Carroll and Ostlie (), Section .) Suppose, then, that you add some energy to such a system and then wait for the system to equilibrate. Does the average total kinetic energy increase or decrease? Explain.
A star can be modeled as a gas of particles that interact with each other only gravitationally. According to the equipartition theorem, the average kinetic energy of the particles in such a star should be , where is the average temperature. Express the total energy of a star in terms of its average temperature, and calculate the heat capacity. Note the sign.
Use dimensional analysis to argue that a star of mass and radius should have a total potential energy of , times some constant of order
Estimate the average temperature of the sun, whose mass is and whose radius is . Assume, for simplicity, that the sun is made entirely of protons and electrons.
An ideal gas is made to undergo the cyclic process shown in the given figure. For each of the steps A, B, and C, determine whether each of the following is positive, negative, or zero: (a) the work done on the gas; (b) the change in the energy content of the gas; (c) the heat added to the gas.
Then determine the sign of each of these three quantities for the whole cycle. What does this process accomplish?
Even at low density, real gases don’t quite obey the ideal gas law. A systematic way to account for deviations from ideal behavior is the virial
expansion,
where the functions , , and so on are called the virial coefficients. When the density of the gas is fairly low, so that the volume per mole is large, each term in the series is much smaller than the one before. In many situations, it’s sufficient to omit the third term and concentrate on the second, whose coefficient is called the second virial coefficient (the first coefficient is 1). Here are some measured values of the second virial coefficient for nitrogen ():
100 | –160 |
200 | –35 |
300 | –4.2 |
400 | 9.0 |
500 | 16.9 |
600 | 21.3 |
Given an example to illustrate why you cannot accurately judge the temperature of an object by how hot or cold it feels to the touch?
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