For a solid, we also define the linear thermal expansion coefficient, α, as the fractional increase in length per degree:

αΔL/LΔT
(a) For steel, α is 1.1 x 10-5 K-1. Estimate the total variation in length of a 1 km steel bridge between a cold winter night and a hot summer day.
(b) The dial thermometer in Figure 1.2 uses a coiled metal strip made of two different metals laminated together. Explain how this works.
(c) Prove that the volume thermal expansion coefficient of a solid is equal to the sum of its linear expansion coefficients in the three directions β=αx + αy + αz. (So for an isotropic solid, which expands the same in all directions, β =3 α .)


Short Answer

Expert verified

a) The total variation in length =0.44m

b) The coil with two metals with different value of α makes the dial thermometer to read the temperature easier.

c) The relationship β=αx+αy+αz is proved.

Step by step solution

01

Part(a)Step1: Given information

coefficient of thermal expansion is α = 1.1 x 10-5 K-1and

length of the steel bridge is L=1 km =1 x 103 m.

02

Part(a) Step2: Explanation

Coefficient of thermal expansion of solid is given as

α=ΔLLΔT

So we can say change in length is given as

ΔL=α×L×ΔT......................(1)

Lets assume the difference between cold winter temperature and hot day temperature is 40K

Substitute the values in the equation (1) we get

ΔL=α×L×ΔTΔL=(1.1×10-5K-1)×(1×103m)×40KΔL=0.44m

So the change in length is 0.44 m .

03

Part(b)Step1: Given information

A dial thermometer with two metal strips with different value of α

04

Part(b)Step2: Explanation

A typical dial thermometer consists of two metal strip coils together with different values of α.

Metal with different value of α will expand differently with change of temperature.

So the coil will make a radial change by changing the temperature.

It is easier to notice the change and hence easier to measure the temperature.

05

Part(c)Step1: Given information

The relationship is given

β=αx+αy+αz

Prove the relationship

06

Part(c)Step2: Explanation

For a non-isotropic solid, they will have different α values, i.e.,αx , αy , αz

Which can be defined as, which are Coefficients of Linear expansion in all three directions are

αx=ΔxxΔT,αy=ΔyyΔT,αz=ΔzzΔT

Where x,y and z is dimension of solid cube and Δx, Δy and Δz are changes in x, y and z respectively.

Coefficients of volume expansion is given by

β=ΔVVΔT

Volume of rectangular solid is

V = xyz .......................................(1)

Differentiate this equation

ΔV=yzΔx+xΔ(yz)ΔV=yzΔx+xzΔy+xzΔy...........................(2)

Divide equation (2) by V=x y z on both the side, we get

ΔVV=Δxx+Δyy+Δzz..............................(3)

We know αxΔT=Δxx,αyΔT=Δyy,αzΔT=Δzz

Substitute values in equation (3) αxΔT=Δxx,αyΔT=ΔyyandαzΔT=Δzz

ΔVV=αxΔT+αyΔT+αzΔTΔVV=αx+αy+αzΔTΔVVΔT=αx+αy+αz...............................(4)

We know

β=ΔVVΔT............................(5)

From equation (4) and (5) we can conclude that

β=αx+αy+αz

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Most popular questions from this chapter

List all the degrees of freedom, or as many as you can, for a molecule of water vapor. (Think carefully about the various ways in which the molecule can vibrate.)

Make a rough estimate of thermal conductivity of helium at room temperature. Discuss your result, explaining why it differs the value for air

Make a rough estimate of the total rate of conductive heat loss through the windows, walls, floor, and roof of a typical house in a cold climate. Then estimate the cost of replacing this lost energy over a month. If possible, compare your estimate to a real utility bill. (Utility companies measure electricity by the kilowatt-hour, a unit equal to MJ. In the United States, natural gas is billed in terms, where 1 therm = 105 Btu. Utility rates vary by region; I currently pay about 7 cents per kilowatt-hour for electricity and 50 cents per therm for natural gas.)

Measured heat capacities of solids and liquids are almost always at constant pressure, not constant volume. To see why, estimate the pressure needed to keep Vfixed as Tincreases, as follows.

(a) First imagine slightly increasing the temperature of a material at constant pressure. Write the change in volume,dV1, in terms of dTand the thermal expansion coefficient βintroduced in Problem 1.7.

(b) Now imagine slightly compressing the material, holding its temperature fixed. Write the change in volume for this process, dV2, in terms of dPand the isothermal compressibility κT, defined as

κT1VVPT

(c) Finally, imagine that you compress the material just enough in part (b) to offset the expansion in part (a). Then the ratio of dPtodTis equal to (P/T)V, since there is no net change in volume. Express this partial derivative in terms of βandκT. Then express it more abstractly in terms of the partial derivatives used to define βandκT. For the second expression you should obtain

PTV=(V/T)P(V/P)T

This result is actually a purely mathematical relation, true for any three quantities that are related in such a way that any two determine the third.

(d) Compute β,κT,and(P/T)Vfor an ideal gas, and check that the three expressions satisfy the identity you found in part (c).

(e) For water at 25C,β=2.57×104K1andκT=4.52×1010Pa1. Suppose you increase the temperature of some water from 20Cto30C. How much pressure must you apply to prevent it from expanding? Repeat the calculation for mercury, for which (at25C)β=1.81×104K1andκT=4.04×1011Pa1

Given the choice, would you rather measure the heat capacities of these substances at constant vor at constant p?

Even at low density, real gases don’t quite obey the ideal gas law. A systematic way to account for deviations from ideal behavior is the virial

expansion,

PVnRT(1+B(T)(V/n)+C(T)(V/n)2+)

where the functions B(T), C(T), and so on are called the virial coefficients. When the density of the gas is fairly low, so that the volume per mole is large, each term in the series is much smaller than the one before. In many situations, it’s sufficient to omit the third term and concentrate on the second, whose coefficient B(T)is called the second virial coefficient (the first coefficient is 1). Here are some measured values of the second virial coefficient for nitrogen (N2):

T(K)
B(cm3/mol)
100–160
200–35
300–4.2
4009.0
50016.9
60021.3
  1. For each temperature in the table, compute the second term in the virial equation, B(T)/(V/n), for nitrogen at atmospheric pressure. Discuss the validity of the ideal gas law under these conditions.
  2. Think about the forces between molecules, and explain why we might expect B(T)to be negative at low temperatures but positive at high temperatures.
  3. Any proposed relation between P, V, andT, like the ideal gas law or the virial equation, is called an equation of state. Another famous equation of state, which is qualitatively accurate even for dense fluids, is the van der Waals equation,
    (P+an2V2)(Vnb)=nRT
    where a and b are constants that depend on the type of gas. Calculate the second and third virial coefficients (Band C) for a gas obeying the van der Waals equation, in terms of aand b. (Hint: The binomial expansion says that (1+x)p1+px+12p(p1)x2, provided that |px|1. Apply this approximation to the quantity [1(nb/V)]1.)
  4. Plot a graph of the van der Waals prediction for B(T), choosing aand bso as to approximately match the data given above for nitrogen. Discuss the accuracy of the van der Waals equation over this range of conditions. (The van der Waals equation is discussed much further in Section 5.3.)
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