Chapter 3: Q. 3.12 (page 97)
Estimate the change in the entropy of the universe due to heat escaping from your home on a cold winter day.
Short Answer
The entropy change on a cold winter day can be estimated to be.
Chapter 3: Q. 3.12 (page 97)
Estimate the change in the entropy of the universe due to heat escaping from your home on a cold winter day.
The entropy change on a cold winter day can be estimated to be.
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Get started for freeSuppose you have a mixture of gases (such as air, a mixture of nitrogen and oxygen). The mole fraction of any species is defined as the fraction of all the molecules that belong to that species: . The partial pressure of species is then defined as the corresponding fraction of the total pressure: . Assuming that the mixture of gases is ideal, argue that the chemical potential of species in this system is the same as if the other gases were not present, at a fixed partial pressure .
Can a "miserly" system, with a concave-up entropy-energy graph, ever be in stable thermal equilibrium with another system? Explain.
Verify every entry in the third line of Table 3.2 (starting with .
Consider a monatomic ideal gas that lives at a height z above sea level, so each molecule has potential energy in addition to its kinetic energy.
(a) Show that the chemical potential is the same as if the gas were at sea level, plus an additional term :
(You can derive this result from either the definition or the formula
(b) Suppose you have two chunks of helium gas, one at sea level and one at height z, each having the same temperature and volume. Assuming that they are in diffusive equilibrium, show that the number of molecules in the higher chunk is
in agreement with the result of Problem 1.16.
Use a computer to study the entropy, temperature, and heat capacity of an Einstein solid, as follows. Let the solid contain 50 oscillators (initially), and from 0 to 100 units of energy. Make a table, analogous to Table 3.2, in which each row represents a different value for the energy. Use separate columns for the energy, multiplicity, entropy, temperature, and heat capacity. To calculate the temperature, evaluate for two nearby rows in the table. (Recall that for some constant .) The heat capacity can be computed in a similar way. The first few rows of the table should look something like this:
(In this table I have computed derivatives using a "centered-difference" approximation. For example, the temperature is computed as .) Make a graph of entropy vs. energy and a graph of heat capacity vs. temperature. Then change the number of oscillators to 5000 (to "dilute" the system and look at lower temperatures), and again make a graph of heat capacity vs. temperature. Discuss your prediction for the heat capacity, and compare it to the data for lead, aluminum, and diamond shown in Figure 1.14. Estimate the numerical value of in electron-volts, for each of those real solids.
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