Chapter 3: Q. 3.12 (page 97)
Estimate the change in the entropy of the universe due to heat escaping from your home on a cold winter day.
Short Answer
The entropy change on a cold winter day can be estimated to be.
Chapter 3: Q. 3.12 (page 97)
Estimate the change in the entropy of the universe due to heat escaping from your home on a cold winter day.
The entropy change on a cold winter day can be estimated to be.
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Get started for freeUse a computer to study the entropy, temperature, and heat capacity of an Einstein solid, as follows. Let the solid contain 50 oscillators (initially), and from 0 to 100 units of energy. Make a table, analogous to Table 3.2, in which each row represents a different value for the energy. Use separate columns for the energy, multiplicity, entropy, temperature, and heat capacity. To calculate the temperature, evaluate for two nearby rows in the table. (Recall that for some constant .) The heat capacity can be computed in a similar way. The first few rows of the table should look something like this:
(In this table I have computed derivatives using a "centered-difference" approximation. For example, the temperature is computed as .) Make a graph of entropy vs. energy and a graph of heat capacity vs. temperature. Then change the number of oscillators to 5000 (to "dilute" the system and look at lower temperatures), and again make a graph of heat capacity vs. temperature. Discuss your prediction for the heat capacity, and compare it to the data for lead, aluminum, and diamond shown in Figure 1.14. Estimate the numerical value of in electron-volts, for each of those real solids.
In solid carbon monoxide, each CO molecule has two possible orientations: CO or OC. Assuming that these orientations are completely random (not quite true but close), calculate the residual entropy of a mole of carbon monoxide.
Sketch (or use a computer to plot) a graph of the entropy of a two-state paramagnet as a function of temperature. Describe how this graph would change if you varied the magnetic field strength.
In the text I showed that for an Einstein solid with three oscillators and three units of energy, the chemical potential is (where is the size of an energy unit and we treat each oscillator as a "particle"). Suppose instead that the solid has three oscillators and four units of energy. How does the chemical potential then compare to ? (Don't try to get an actual value for the chemical potential; just explain whether it is more or less than .)
Use Table 3.1 to compute the temperatures of solid A and solid B when . Then compute both temperatures when . Express your answers in terms of , and then in kelvins assuming that .
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