In Problem 1.55 you used the virial theorem to estimate the heat capacity of a star. Starting with that result, calculate the entropy of a star, first in terms of its average temperature and then in terms of its total energy. Sketch the entropy as a function of energy, and comment on the shape of the graph.

Short Answer

Expert verified

The required expression for the entropy of a star is S=-32NKln2U3NK+f(N,V)and the graph can be sketched as below.

Step by step solution

01

Given Information

The heat capacity of a star that was estimated using the virial theorem is given as:

CV=-32NK

Where,

Nis the number of particles (typically dissociated protons and electrons).

The negative sign symbolizes that it is a gravitational bound system.

02

Calculation

The change in entropy is given as:

S=CV(T)TdT

Where,

CV= specific heat

T= Temperature in Kelvin

By substituting the value of CVin the above equation, we get,

S=-32NKTdTS=-32NK1TdTS=-32NKTln(T)+f(N,V)..........(1)

In this equation, fis the function of Nand volume V.

Total energy of gravitationally bound system is negative and from the virial theorem, it is found that:

U=-K=-32NKT

By rearranging the terms, we get,

T=-2U3NK

By substituting this value in equation (1), we get,

S=-32NKln2U3NK+f(N,V)

For plotting the graph, let us further simplify the above equation,

S=-32NKln(U)-32NKln3NK2+f(N,V)S=-32NKln(U)+g(N,V)

From the above equation, the graph can be plotted as below:

03

Final answer

Hence, the required expression is: S=-32NKln2U3NK+f(N,V)

The graph of entropy as a function can be sketched as follow:

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Most popular questions from this chapter

Experimental measurements of heat capacities are often represented in reference works as empirical formulas. For graphite, a formula that works well over a fairly wide range of temperatures is (for one mole)

CP=a+bT-cT2

where a=16.86J/K,b=4.77×10-3J/K2, and c=8.54×105J·K. Suppose, then, that a mole of graphite is heated at constant pressure from 298Kto 500K. Calculate the increase in its entropy during this process. Add on the tabulated value of S(298K)(from the back of this book) to obtain S(500K).

Starting with the result of Problem 2.17, find a formula for the temperature of an Einstein solid in the limit qN. Solve for the energy as a function of temperature to obtain U=Nϵe-ϵ/kT (whereϵ is the size of an energy unit).

In the text I showed that for an Einstein solid with three oscillators and three units of energy, the chemical potential is μ=-ϵ(where ϵis the size of an energy unit and we treat each oscillator as a "particle"). Suppose instead that the solid has three oscillators and four units of energy. How does the chemical potential then compare to -ϵ ? (Don't try to get an actual value for the chemical potential; just explain whether it is more or less than -ϵ.)

Show that the entropy of a two-state paramagnet, expressed as a function of temperature, is S=Nk[ln(2coshx)xtanhx], where x=μB/kT. Check that this formula has the expected behavior as T0and T.

A liter of air, initially at room temperature and atmospheric pressure, is heated at constant pressure until it doubles in volume. Calculate the increase in its entropy during this process.

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