In Problem 1.55 you used the virial theorem to estimate the heat capacity of a star. Starting with that result, calculate the entropy of a star, first in terms of its average temperature and then in terms of its total energy. Sketch the entropy as a function of energy, and comment on the shape of the graph.

Short Answer

Expert verified

The required expression for the entropy of a star is S=-32NKln2U3NK+f(N,V)and the graph can be sketched as below.

Step by step solution

01

Given Information

The heat capacity of a star that was estimated using the virial theorem is given as:

CV=-32NK

Where,

Nis the number of particles (typically dissociated protons and electrons).

The negative sign symbolizes that it is a gravitational bound system.

02

Calculation

The change in entropy is given as:

S=CV(T)TdT

Where,

CV= specific heat

T= Temperature in Kelvin

By substituting the value of CVin the above equation, we get,

S=-32NKTdTS=-32NK1TdTS=-32NKTln(T)+f(N,V)..........(1)

In this equation, fis the function of Nand volume V.

Total energy of gravitationally bound system is negative and from the virial theorem, it is found that:

U=-K=-32NKT

By rearranging the terms, we get,

T=-2U3NK

By substituting this value in equation (1), we get,

S=-32NKln2U3NK+f(N,V)

For plotting the graph, let us further simplify the above equation,

S=-32NKln(U)-32NKln3NK2+f(N,V)S=-32NKln(U)+g(N,V)

From the above equation, the graph can be plotted as below:

03

Final answer

Hence, the required expression is: S=-32NKln2U3NK+f(N,V)

The graph of entropy as a function can be sketched as follow:

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with Vaia!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

Use the thermodynamic identity to derive the heat capacity formula

CV=TSTV

which is occasionally more convenient than the more familiar expression in terms of U. Then derive a similar formula for CP, by first writing dHin terms of dSand dP.

Show that the entropy of a two-state paramagnet, expressed as a function of temperature, is S=Nk[ln(2coshx)xtanhx], where x=μB/kT. Check that this formula has the expected behavior as T0and T.

Experimental measurements of heat capacities are often represented in reference works as empirical formulas. For graphite, a formula that works well over a fairly wide range of temperatures is (for one mole)

CP=a+bT-cT2

where a=16.86J/K,b=4.77×10-3J/K2, and c=8.54×105J·K. Suppose, then, that a mole of graphite is heated at constant pressure from 298Kto 500K. Calculate the increase in its entropy during this process. Add on the tabulated value of S(298K)(from the back of this book) to obtain S(500K).

Use the result of Problem 2.42 to calculate the temperature of a black hole, in terms of its mass M. (The energy is Mc2. ) Evaluate the resulting expression for a one-solar-mass black hole. Also sketch the entropy as a function of energy, and discuss the implications of the shape of the graph.

As shown in Figure 1.14, the heat capacity of diamond near room temperature is approximately linear in T. Extrapolate this function up to 500K, and estimate the change in entropy of a mole of diamond as its temperature is raised from298K to 500K. Add on the tabulated value at298K (from the back of this book) to obtain S(500K).

See all solutions

Recommended explanations on Physics Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.

Sign-up for free