A bit of computer memory is some physical object that can be in two different states, often interpreted as 0 and 1. A byte is eight bits, a kilobyte is 1024=210bytes, a megabyte is 1024 kilobytes, and a gigabyte is 1024 megabytes.

(a) Suppose that your computer erases or overwrites one gigabyte of memory, keeping no record of the information that was stored. Explain why this process must create a certain minimum amount of entropy, and calculate how much.

(b) If this entropy is dumped into an environment at room temperature, how much heat must come along with it? Is this amount of heat significant?

Short Answer

Expert verified

(a) The entropy created is 8.22×10-14JK-1.

(b) The amount of heat generated is2.45×10-11J.

Step by step solution

01

Part (a) Step 1: Given Information

Computer memory can be classified in two different states, often defined as 0 and 1 .

1byte=8bits1kilobyte=1024(=210)bytes1megabyte=1024(=210)kilobytes1gigabyte=1024(=210)megabytes

02

Part (a) Step 2: Calculation

The expression for entropy with multiplicity Ωis given as:

S=kln(Ω).........(1)

Where,

k= Boltzmann constant

N= the number of atoms

Ω= multiplicity

If a single bit of computer memory is taken to be a particle with two states, then a collection of Nbits has a particle 2N, and its entropy may be determined using equation (1)

S=kln(Ω)=Nkln(2)...(2)

If a gigabyte 230bytes233bits,soN=233is used to store certain information and later erased without a backup, 233bitsof information is lost indirectly. If the original information is replaced with a known pattern, it appears that the entropy hasn't changed because the state has only changed. If the original information containing the random pattern is deleted, entropy is likely to increase.

The amount of entropy generated by randomizing gigabytes can be given as:

S=Nkln(2)=233kln(2).(3)

By substituting the value of kin the above equation, we get,

role="math" localid="1647267704138" S=2331.38×10-23ln(2)S=8.22×10-14JK-1

03

Part (a) Step 3: Final answer

Hence, the required entropy is8.22×10-14JK-1.

04

Part (b) Step 1: Given Information

Room temperature =T=298K

Entropy created=S=8.22×10-14JK-1

05

Part (b) Step 2: Calculation

The amount of heat is given as:

Q=TΔS

By substituting the values in the above equation, we get,

Q=298×8.22×10-14Q=2.45×10-11J

06

Part (b) Step 3: Final answer

Hence, the amount of heat generated is2.45×10-11J.

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Most popular questions from this chapter

When the sun is high in the sky, it delivers approximately 1000 watts of power to each square meter of earth's surface. The temperature of the surface of the sun is about 6000K, while that of the earth is about 300K.

(a) Estimate the entropy created in one year by the flow of solar heat onto a square meter of the earth.

(b) Suppose you plant grass on this square meter of earth. Some people might argue that the growth of the grass (or of any other living thing) violates the second law of thermodynamics, because disorderly nutrients are converted into an orderly life form. How would you respond?

Use the definition of temperature to prove the zeroth law of thermodynamics, which says that if system A is in thermal equilibrium with system B, and system B is in thermal equilibrium with system C, then system A is in thermal equilibrium with system C. (If this exercise seems totally pointless to you, you're in good company: Everyone considered this "law" to be completely obvious until 1931, when Ralph Fowler pointed out that it was an unstated assumption of classical thermodynamics.)

Polymers, like rubber, are made of very long molecules, usually tangled up in a configuration that has lots of entropy. As a very crude model of a rubber band, consider a chain of N links, each of length (see Figure 3.17). Imagine that each link has only two possible states, pointing either left or right. The total length L of the rubber band is the net displacement from the beginning of the first link to the end of the last link.

(a) Find an expression for the entropy of this system in terms of N and NR, the number of links pointing to the right.
(b) Write down a formula for L in terms of N and NR.
(c) For a one-dimensional system such as this, the length L is analogous to the volume V of a three-dimensional system. Similarly, the pressure P is replaced by the tension force F. Taking F to be positive when the rubber band is pulling inward, write down and explain the appropriate thermodynamic identity for this system.
(d) Using the thermodynamic identity, you can now express the tension force F in terms of a partial derivative of the entropy. From this expression, compute the tension in terms of L, T, N, and .
(e) Show that when L << N, the tension force is directly proportional to L (Hooke's law).
(f) Discuss the dependence of the tension force on temperature. If you increase the temperature of a rubber band, does it tend to expand or contract? Does this behavior make sense?
(g) Suppose that you hold a relaxed rubber band in both hands and suddenly stretch it. Would you expect its temperature to increase or decrease? Explain. Test your prediction with a real rubber band (preferably a fairly heavy one with lots of stretch), using your lips or forehead as a thermometer. (Hint: The entropy you computed in part (a) is not the total entropy of the rubber band. There is additional entropy associated with the vibrational energy of the molecules; this entropy depends on U but is approximately independent of L.)

An ice cube (mass 30g)0°Cis left sitting on the kitchen table, where it gradually melts. The temperature in the kitchen is 25°C.

(a) Calculate the change in the entropy of the ice cube as it melts into water at 0°C. (Don't worry about the fact that the volume changes somewhat.)

(b) Calculate the change in the entropy of the water (from the melted ice) as its temperature rises from 0°Cto 25°C.

(c) Calculate the change in the entropy of the kitchen as it gives up heat to the melting ice/water.

(d) Calculate the net change in the entropy of the universe during this process. Is the net change positive, negative, or zero? Is this what you would expect?

Sketch (or use a computer to plot) a graph of the entropy of a two-state paramagnet as a function of temperature. Describe how this graph would change if you varied the magnetic field strength.

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