Figure 3.3 shows graphs of entropy vs. energy for two objects, A and B. Both graphs are on the same scale. The energies of these two objects initially have the values indicated; the objects are then brought into thermal contact with each other. Explain what happens subsequently and why, without using the word "temperature."

Short Answer

Expert verified

Since the slope SUis different for both objects, the combined system will evolve by exchanging energy until the slopes become equal.

Step by step solution

01

Concept Introduction

If two objects are in thermal equilibrium, their temperatures are said to be the same. It can be expressed in terms of the system's entropy and energy, the measure of randomness being the entropy. It is determined by the amount of energy that is not available for work.

02

Explanation

Mathematically, temperature can be defined as:

1T=SU

Where,

Sis the change in entropy and Uis the change in the internal energy of the body.

Hence, a graph reflecting these values can be used to study the temperature of that body.

Conversely, it can also be said that if the slope SUof bodies are same, their temperatures would be same.

From the figure, it can be seen that the slope SUof A is greater than that of B. The system will evolve through energy exchange until the slopes are equal. Assume that UA+UB=Utotal, i.e. that energy is exchanged in both directions. As a result, if UAis increased, UBmust be reduced in equal measure, and vice versa. In this situation, one option to make the slope equal is to decrease the slope for B and increase the slope for A, which may be accomplished by reducing UBand raising by the same amount. System B will transfer some energy to A until the slopes are equal. The temperature is referred to as the slope in this case.

03

Final answer

As a result, the slope SUof A is greater than that of B, and the system will evolve by exchanging energy until the slopes are equal.

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Most popular questions from this chapter

When the sun is high in the sky, it delivers approximately 1000 watts of power to each square meter of earth's surface. The temperature of the surface of the sun is about 6000K, while that of the earth is about 300K.

(a) Estimate the entropy created in one year by the flow of solar heat onto a square meter of the earth.

(b) Suppose you plant grass on this square meter of earth. Some people might argue that the growth of the grass (or of any other living thing) violates the second law of thermodynamics, because disorderly nutrients are converted into an orderly life form. How would you respond?

Use the thermodynamic identity to derive the heat capacity formula

CV=TSTV

which is occasionally more convenient than the more familiar expression in terms of U. Then derive a similar formula for CP, by first writing dHin terms of dSand dP.

In Section 2.5 I quoted a theorem on the multiplicity of any system with only quadratic degrees of freedom: In the high-temperature limit where the number of units of energy is much larger than the number of degrees of freedom, the multiplicity of any such system is proportional to UNf/2, whereNf is the total number of degrees of freedom. Find an expression for the energy of such a system in terms of its temperature, and comment on the result. How can you tell that this formula forΩ cannot be valid when the total energy is very small?

In order to take a nice warm bath, you mix 50 liters of hot water at 55°C with 25 liters of cold water at 10°C. How much new entropy have you created by mixing the water?

Starting with the result of Problem 3.5, calculate the heat capacity of an Einstein solid in the low-temperature limit. Sketch the predicted heat capacity as a function of temperature.

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