In Problem 2.32you computed the entropy of an ideal monatomic gas that lives in a two-dimensional universe. Take partial derivatives with respect to U,A, and N to determine the temperature, pressure, and chemical potential of this gas. (In two dimensions, pressure is defined as force per unit length.) Simplify your results as much as possible, and explain whether they make sense.

Short Answer

Expert verified

T=UNkP=NkTAμ=kTlnVN2mmkTh23/22

Step by step solution

01

Given Information

The entropy of an ideal gas is,

S=Nkln2πmAU(Nh)2+2

02

Calculation

To get the temperature, we partial differentiate with respect to U,

1T=SUA,N1T=UNkln2mmAU(Nh)2+2=Nk(Nh)22xmAU2nmA(Nh)2=NkUT=UNk

Partial differentiating with respect to A, we get the pressure as,

P=TSAU,N=TANkln2mnUU(Nh)2+2=NkT(Nh)22πnAU×2mmU(Nh)2=NkTA

03

Chemical Potential

Partial differentiating the entropy with respect to N, we get the chemical potential as,

μ=TSdNUA=TdNNkln2πmAU(Nh)2+2=kTln2πmAU(Nh)2+2kTN(Nh)22πmAU×2πnAUh2×2N3=kTln2mmAU(Nh)2+2+2kT=kTln2mmAU(Nh)2+22=kTln2mmAU(Nh)2=kTln2mmA(NkT)(Nh)2=kTlnVN2πmLTN23/2

04

Conclusion

The temperature, pressure and entropy are given by:

T=UNkP=NkTAμ=kTlnVN2πmkTh232

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Most popular questions from this chapter

Sketch a qualitatively accurate graph of the entropy of a substance (perhapsH2O ) as a function of temperature, at fixed pressure. Indicate where the substance is solid, liquid, and gas. Explain each feature of the graph briefly.

A liter of air, initially at room temperature and atmospheric pressure, is heated at constant pressure until it doubles in volume. Calculate the increase in its entropy during this process.

A cylinder contains one liter of air at room temperature ( 300K) and atmospheric pressure 105N/m2. At one end of the cylinder is a massless piston, whose surface area is 0.01m2. Suppose that you push the piston in very suddenly, exerting a force of 2000N. The piston moves only one millimeter, before it is stopped by an immovable barrier of some sort.

(a) How much work have you done on this system?

(b) How much heat has been added to the gas?

(c) Assuming that all the energy added goes into the gas (not the piston or cylinder walls), by how much does the internal energy of the gas increase?

(d) Use the thermodynamic identity to calculate the change in the entropy of the gas (once it has again reached equilibrium).

Can a "miserly" system, with a concave-up entropy-energy graph, ever be in stable thermal equilibrium with another system? Explain.

Use the result of Problem 2.42 to calculate the temperature of a black hole, in terms of its mass M. (The energy is Mc2. ) Evaluate the resulting expression for a one-solar-mass black hole. Also sketch the entropy as a function of energy, and discuss the implications of the shape of the graph.

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